Abstract
The microwave characteristics of the BaTi4O9-BaPr2Ti4O12 system were investigated, including its microstructure and infrared reflection spectroscopy. It was found that this system is entirely composed of two phases, BaTi4O9 and BaPr2Ti4O12, and it is suggested that the lattices of each phase are well matched obliquely at the interface in the sintered ceramics. The dielectric properties are compared with calculated values deduced from the mixing relations of the two components. Furthermore, the infrared reflection spectra of this system were analysed with the factorized form of the dielectric function, for the purpose of studying the applicability of the reflection analysis technique to this mixed phase system.
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S. Kawashima, M. Nishida, I. Ueda and H. Ouchi, J. Amer. Ceram. Soc. 66 (1983) 421.
H. M. O'Bryan, Jr, J. Thomson, Jr and J. K. Plourde, ibid. 57 (1974) 450.
S. Kawashima, M. Nishida. I. Ueda and H. Ouchi, Paper presented at the 87th Annual Meeting, American Ceramic Society, Cincinnati, OH, 6 May 1985 (Electronics Division Paper No. 15-E85).
A. E. Paladino, J. Amer. Ceram. Soc. 54 (1971) 1689.
K. Fukuda, R. Kitoh and I. Awai, Jpn J. Appl. Phys. 32 (1993) 4584.
S. Nishigaki, H. Kato, S. Yano and R. Kamimura, Amer. Ceram. Soc. Bull. 66 (1987) 1405.
F. Gervais and B. Piriou, Phys. Rev. B10 (1974) 2038.
J. L. Servoin, F. Gervais, A. M. Quittet and Y. Luspin, ibid. B21 (1980) 2038.
R. M. Lyddane, R. G. Sachs and E. Teller, ibid. 59 (1951) 673.
T. Kurosawa, J. Phys. Soc. Jpn 16 (1961) 1298.
K. Wakino, M. Murata and H. Tamura, J. Amer. Ceram. Soc. 69 (1986) 34.
T. Negas, R. S. Roth, H. S. Parker and D. Minor, J. Solid State Chem. 9 (1974) 297.
D. Kolar, S. Gaberscek, B. Volavsek, H. S. Parker and R. S. Roth, ibid. 38 (1981) 158.
JCPDS cards: 35–228 for BaPr2Ti4O12, 34–70 for BaTi4O9.
A. M. Gens, M. B. Varfolomeev, V. S. Kostromarov and S. S. Korovin, Russian J. Inorg. Chem. 26 (1981) 482.
M. B. Varfolomeev, A. S. Mironov, V. S. Kostomarov, L. A. Golubtsova and T. A. Zolotova, Russian J. Inorg. Chem. 33 (1988) 607.
W. G. Spitzer, R. C. Miller, D. A. Kleinman and L. E. Howarth, Phys. Rev. 126 (1962) 1710.
S. G. Mhaisalkar, D. W. Readey, S. A. Akbar, P. K. Dutta, M. J. Sumnar, and R. Rokhlin, J. Solid State Chem. 95 (1991) 275.
R. Kudesia, A. E. Mchale, R. A. Condrate, Sr and L. R. Snyder, J. Mater. Sci. 28 (1993) 6569.
K. Fukuda, I. Fujii, R. Kitoh, Y. Cho and I. Awai, Jpn J. Appl. Phys. 32 (1993) 1712.
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Fukuda, K., Kitoh, R. & Awai, I. Microwave characteristics of mixed phases of BaTi4O9-BaPr2Ti4O12 ceramics. JOURNAL OF MATERIALS SCIENCE 30, 1209–1216 (1995). https://doi.org/10.1007/BF00356121
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DOI: https://doi.org/10.1007/BF00356121