Skip to main content
Log in

Rare-earth modified chromium-aluminide coatings applied by pack cementation method on low-alloy steels

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

In metallurgical practice the presence of a minor amount of certain elements can induce significant changes in a material's physical, mechanical and chemical properties. In this paper we present the nature, morphology and properties of protective coatings containing Cr, Al and minor amounts of a rare earth element, applied on 2.25 Cr-1 Mo low-alloy steel. The coating technology, pack cementation, was used to achieve the simultaneous deposition of the coating elements in a one step process. Cyclic oxidation, conducted in air at 800 °C, induced thermal stresses on the alloy samples, promoting the tendency of the oxide scales formed to spall. The rare earth modified coatings, under these conditions showed the beneficial effects of the rare earth addition. These coatings, upon exposure, developed an adherent oxide scale which had better properties, and retarded the alloy's degradation. This lead to a significant reduction in the overall oxidation rate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. E. King, in “Materials Science Forum”, Vol. 43, edited by W. E. King (Trans Tech. Publications Ltd. Switzerland, 1989) p. VII.

    Google Scholar 

  2. J. A. Ramanarayanan, M. Raghavan and R. Petkovic-Luton, J. Electrochem. Soc. 131 (1984) 923.

    Article  CAS  Google Scholar 

  3. A. D. Zervaki, G. N. Haidemenopoulos and D. N. Tsipas, in Proceedings of the Third International Conference on Advances on Coatings and Surface Engineering, Newcastle upon Tyne, May 1992, edited by P. K. Datta and J. S. Gray (Royal Society of Chemistry, Cambridge, UK 1993) p. 71.

    Google Scholar 

  4. R. Bianco and R. A. Rapp, J. Electrochem. Soc. 140 (1993) 1191.

    Article  CAS  Google Scholar 

  5. P. A. Choquet, E. R. Naylor and R. A. Rapp, Mater. Sci. Engng. A 121 (1989) 413.

    Article  Google Scholar 

  6. F. D. Geib and R. A. Rapp, Oxidation of Metals 40 (1993) 213.

    Article  CAS  Google Scholar 

  7. B. A. Print and L. W. Hobbs, J. Electrochem. Soc. 141 (1994) 2443.

    Article  Google Scholar 

  8. J. Singh and J. Mazumder, Acta Metall. 35 (1987) 1995.

    Article  CAS  Google Scholar 

  9. G. W. Goward and R. W. Cannon, J. Engng for Gas Turbines and Power 110 (1988) 150.

    Article  CAS  Google Scholar 

  10. M. J. Bennet and D. P. Moon, in Proceedings of the European Colloquium on the Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys, Petten, Dec. 1988, edited by E. Lang (Elsevier Applied Science, Brussels, 1989) p. 111.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kipkemoi, J., Tsipas, D. Rare-earth modified chromium-aluminide coatings applied by pack cementation method on low-alloy steels. JOURNAL OF MATERIALS SCIENCE 31, 6247–6250 (1996). https://doi.org/10.1007/BF00354445

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00354445

Keywords

Navigation