Abstract
The influence of notching speed on the fatigue behaviour of crystalline and amorphous polyethylene terephthalate (PET) was investigated. A clear precrack adjacent to the notch tip was found after each crystalline sample was notched, and the precrack length increased when the samples were notched at higher speeds. The failure time, t f, decreased significantly for samples with longer precrack lengths, and the decrease in t f due to faster notching speeds was significantly lower for samples of high average molecule weight and calculated tie-molecule density. In contrast, a heart-shaped damaged structure surrounding the notch tip was observed after each amorphous sample was notched, and the size of the damaged zone, adjacent to the notch tip, increased significantly with the notching speed. Furthermore, the time to failure of each amorphous sample increased significantly as the notching speed increased. In fact, most of the increase in t f is due to an increase in the initiation period, t i. This significant increase in t i is attributed to the larger damaged zone caused by higher notching speeds.
Similar content being viewed by others
References
R. W. HERTZBERG and J. A. MANSON, in “Fatigue of engineering plastics” (Academic Press, New York 1980).
J. A. MANSON and R. W. HERTZBERG, Ency. Polym. Sci. Engng. 7 (1986) 378.
S. K. BHATTACHARYA and N. BROWN, J. Mater. Sci. 19 (1984) 2519.
S. K. BHATTACHARYA and N. BROWN, J. Mater. Sci. 20 (1985) 2767.
X. LU and N. BROWN, J. Mater. Sci. 21 (1986) 2423.
X. LU and N. BROWN, J. Mater. Sci. 21 (1986) 4081.
X. LU, X. WANG and N. BROWN, J. Mater. Sci. 23 (1988) 643.
N. BROWN and X. WANG, Polymer 29 (1988) 463.
Y. HUANG and N. BROWN, J. Mater. Sci. 23 (1988) 3648.
X. LU, R. QIAN and N. BROWN, J. Mater. Sci 26 (1991) 881.
Plane-Strain Fracture Toughness of Metallic Materials, ASTM E399-83, (American Society for Testing and Materials, Philadelphia 1989).
Measurement of Fatigue Crack Growth Rates, ASTM E647-88a, (American Society for Testing and Materials, Philadelphia, 1989).
K. WEISSKOPF, J. Polym. Sci., A 26 (1988) 1919.
P. E. SLADE, T. A. ORFINO, in “Analytical calorimetry”, edited by R. S. PORTER, J. F. JOHNSON, (Plenum Press, New York, 1968) p. 63.
J. D. HOFFMAN, G. T. DAVIS and J. I. LAURITZEN, “Treatise on solid state chemistry”, Vol. 3, edited by N. B. HANNYAY (Plenum Press, New York, 1975).
R. de P. DAUBENY, C. W. BUNN, C. J. BROWN, Proc. Roy. Soc. A 226 (1954) 531.
G. C. ALFONSO, E. PEDEMONTE and L. PONZETTI, Polymer 20 (1979) 104.
H. D. KEITH, F. J. PADDEN Jr, and R. G. VADIMSKY, J. Polym. Sci., A-2 4 (1966) 267.
H. D. KEITH, F. J. PADDEN Jr, and R. G. VADIMSKY, J. Appl. Phys. 37 (1966) 4027.
H. D. KEITH, F. J. PADDEN Jr, and R. G. VADIMSKY, J. Appl. Phys. 42 (1971) 4585.
R. G. VADIMSKY, H. D. KEITH, and F. J. PADDEN, J. Polym. Sci., A-2 7 (1969) 1367.
H. A. DAVIS, J. Polym. Sci. A-2 4 (1966) 1009.
S. NAGOU and K. AZUMA, J. Macromol. Sci., Phys. Ed. 16 (1979) 435.
E. S. CLARK, S. P. E. J. 23 (1967) 46.
H. D. KEITH, F. J. PADDEN, Jr., and R. G. VADIMSKY, J. Polym. Sci., Polym. Phys. Ed. 18 (1980) 2307.
E. W. FISCHER, K. HAHN, J. KUGLER, U. STRUTH, and R. BOM, J. Polym. Sci., Polym. Phys. Ed. 22 (1984) 1491.
V. V. ZHIZHENKOV and E. A. EGOROV, J. Polym. Sci., Polym. Phys. Ed. 22 (1984) 117.
N. BROWN and I. M. WARD, J. Mater. Sci. 18 (1983) 1413.
J. T. YEH and J. RUNT, J. Polym. Sci., Polym. Phys. Ed., 29 (1991) 371.
W. W. GRAESSLEY, Adv. Polym. Sci. 16 (1974) 55.
J. T. YEH and J. RUNT, J. Mater. Sci. 24 (1989) 1421.
Y. L. HUANG and N. BROWN, J. Mater. Sci. 23 (1991) 3648.
Y. L. KEITH, F. J. PADDEN, Jr., and R. G. VADIMSKY, J. Appl. Phys. 42 (1971) 4585.
S. WELLINGHOFF and E. BAER, J. Macromol. Sci. Phys. B 11 (1975) 367.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yeh, J.T., Lin, Y.T. Effect of notching speed on dynamic fatigue behaviour of polyethylene terephthalate polymers. JOURNAL OF MATERIALS SCIENCE 28, 3900–3910 (1993). https://doi.org/10.1007/BF00353198
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00353198