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La2Zr2O7 formed at ceramic electrode/YSZ contacts

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Abstract

Strontium-doped LaCoO3 or LaMnO3 materials have been studied for use as cathodes for solid oxide fuel cells (SOFCs). This choice relies on the required properties and competitive cost. However, formation of reaction products under typical electrode-firing conditions may affect the performance of SOFCs. La2Zr2O7 was detected at YSZ/electrode interfaces. This reaction product was synthesized from powders and characterized to obtain a better understanding of its effects on cell performance. Its structural, thermal, and electrical properties are reported.

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References

  1. Y. TAKEDA, R. KANNO, M. NODA, Y. TOMIDA and O. YAMAMOTO, J. Electrochem. Soc. 134 (1987) 2656.

    Article  CAS  Google Scholar 

  2. A. HAMMOUCHE, E. SIEBERT and A. HAMMOU, Mater. Res. Bull. 24 (1989) 367.

    Article  CAS  Google Scholar 

  3. J. A. LABRINCHA, J. R. FRADE and F. M. B. MARQUES, in “Proceedings of the 2nd International Symposium on SOFCs”, Athens, July 1991, edited by F. GROSS, P. ZEGERS, S. SINGHAL and O. YAMAMOTO (Common European Community, Brussels, 1991) p. 689.

    Google Scholar 

  4. H. YOKOKAWA, N. SAKAI, T. KAWADA and M. DOKIYA, Solid State Ionics 40/41 (1990) 398.

    Article  Google Scholar 

  5. T. H. ETSELL and S. N. FLENGAS, Chem. Rev. 70 (1970) 339.

    Article  CAS  Google Scholar 

  6. M. P. Van DIJK, K. J. de VRIES and A. J. BURGGRAAF, Solid State Ionics 9/10 (1983) 913.

    Article  Google Scholar 

  7. K. SHINOZAKI, J. Amer. Ceram. Soc. 62 (1979) 538.

    Article  CAS  Google Scholar 

  8. F. M. B. MARQUES and G. P. WIRTZ, ibid. 74 (1991) 598.

    Article  CAS  Google Scholar 

  9. Idem., ibid., in press.

    Article  CAS  Google Scholar 

  10. G. P. WIRTZ and F. M. B. MARQUES, ibid., in press.

    Article  Google Scholar 

  11. J. C. C. ABRANTES, J. A. LABRINCHA, F. M. B. MARQUES and J. R. FRADE, in “Ceramics Today — Tomorrow's Ceramics”, Part C, edited by P. VINCENZINI (Elsevier Science, Amsterdam, 1991) p. 2265.

    Google Scholar 

  12. F. BEECH, W. M. JORDAN, C. R. A. CATLOW, A. SANTORO and B. C. H. STEELE, J. Solid State Chem. 77 (1988) 322.

    Article  CAS  Google Scholar 

  13. S. P. S. BADWALE, J. Mater. Sci. 19 (1984) 1767.

    Article  Google Scholar 

  14. J. M. DIXON, L. D. LAGRANGE, U. MERTEN, C. F. MILLER and J. T. PORTER II, J. Electrochem. Soc. 110 (1963) 276.

    Article  CAS  Google Scholar 

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Labrincha, J.A., Frade, J.R. & Marques, F.M.B. La2Zr2O7 formed at ceramic electrode/YSZ contacts. JOURNAL OF MATERIALS SCIENCE 28, 3809–3815 (1993). https://doi.org/10.1007/BF00353183

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