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Fracture behaviour of casein films — II

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Abstract

Casein was grafted with acrylonitrile and with a binary mixture of acrylonitrile and n-butyl methacrylate. Mechanical properties and the fracture of these films were studied at different temperatures. Due to possible transition, fracture behaviour changed ca. 60 °C in both systems. The effect of the polymer (grafted chains and homopolymer) present in the system affected the morphology and the fracture behaviour of casein films grafted with binary mixtures of the monomer.

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References

  1. “Recent advances in polymer blends, grafts and blocks”, edited by L. H. Sperling (Plenum Press, NY, 1974).

  2. A. Noshay and J. E. Mcgrath, “Block copolymers: An overview and critical survey” (Academic, NY, 1977).

    Google Scholar 

  3. G. E. Molar, “Colloidal and morphological behaviour of block and graft copolymer” (Plenum, NY, 1971).

    Google Scholar 

  4. D. Mohan, R. Ganga and S. Rajadurai, Macromol. Chem. 183 (1982) 1659.

    Article  CAS  Google Scholar 

  5. D. Mohan, R. Ganga and S. Rajadurai, J. Poly. Sci. 21 (1983) 3041.

    CAS  Google Scholar 

  6. D. Mohan, R. Ganga and S. Rajadurai, Macromol. Sci. Chem. A20 (1983) 201.

    Article  CAS  Google Scholar 

  7. D. Mohan, R. Ganga and T. Nagabhushanam, J. Appl. Poly. Sci. 25(8) (1980) 1799.

    Article  CAS  Google Scholar 

  8. D. Mohan, R. Ganga, S. Rajadurai, T. Nagabhushanam and K. T. Joseph, J. Appl. Poly. Sci. 29 (1984) 329.

    Article  CAS  Google Scholar 

  9. D. Mohan, R. Ganga, S. Rajadurai, K. Venkatarao and Gorden G. Cameron, J. Poly. Sci. 27 (1989) 2123.

    Article  CAS  Google Scholar 

  10. K. Studoriarski, W. Wyboz and M. Swiekatowski, Przegl Skorzany 38 (1983) 235.

    Google Scholar 

  11. Y. Lakshiminarayan, N. Radhakrishnan, K. Parthasarathy, K. S. V. Srinivasan and K. T. Joseph, Leather Sci. 32 (1985) 134.

    Google Scholar 

  12. D. Mohan, R. Ganga and S. Rajadurai, Leather Sci. 33 (1986) 242.

    CAS  Google Scholar 

  13. S. Valliappan, S. Rajadurai and M. Santhappa, Leather Sci. 22 (1975) 1.

    CAS  Google Scholar 

  14. S. Mohan, R. Ganga and S. Rajadurai, J. Macromol. Sci. Chem. A22 (1985) 75.

    Article  CAS  Google Scholar 

  15. K. Stundriarski, Z. Wilmanski and P. Siwiek, Przegl Skorzany, 38 (1983) 31; via Chemical Abstracts 100 (1984) 23299b.

    Google Scholar 

  16. S. Valliappan, S. Kulasekaran, S. Rajadurai, K. T. Joseph and M. Santhappa, Leather Sci. 23 (1976) 57.

    CAS  Google Scholar 

  17. Kojima Kunihara, Iwabuchi Susuma Kojima and Koichi Tarami Niro, J. Poly. Sci., B 9 (1971) 25.

    Article  Google Scholar 

  18. T. Ota, K. Nanba, K. Tamaki, K. Hamada and A. Yamamoto, Sen'i Gorkkaishi, 31 (1975) T-401; via Chemical Abstracts 84 (1976) 6338x.

    Google Scholar 

  19. T. Ota, K. Nanba and A. Yamamoto, Sen'i Gakkaishi, 31 (1975) T-405; via Chemical Abstracts 84 (1976) 6339y.

    Google Scholar 

  20. Ishii, Koyoshi, Oka Satoru, Seni Gakkaishi, 39 (1983) 479; via Chemical Abstracts 101 24920e.

  21. Tanaka Toshikiyo, Imai Sadao, Kawamura Kumiko, J. P. 51053098 (11 May 1976).

  22. S. Kulasekaran, Y. Lakshiminarayana, S. Rajadurai, K. T. Joseph and M. Santhappa, Leather Sci. 23 (1976) 385.

    CAS  Google Scholar 

  23. Yamamoto, Akira, Ohhara, Konio and Ohtsuka Masamichi, J. P. 46001263 (13 Jan. 1971).

  24. Xia Jinyu, Luo Ning, Xibi Qiuggongye and Xueyuan Xuebao, 3 (1986) 34; via Chemical Abstracts 110 8751f.

  25. K. C. Smeltz and K. Dyer, J. Amer. Chem. Soc. 74 (1952) 263.

    Article  Google Scholar 

  26. N. Somanathan, N. Radhakrishnan, R. Sanjeevi and C. Rami Reddy, Euro. Poly. J. 23 (1987) 489.

    Article  CAS  Google Scholar 

  27. “1980 annual book of ASTM Standards, Part 35 D”, (American Society of Testing of Materials, Philadelphia, 1980) pp. 1708–79.

  28. N. Somanathan, V. Arumugam and R. Sanjeevi, Euro. Poly. J. 23 (1987) 807.

    Google Scholar 

  29. T. S. Casewell and H. K. Nason, Modern Plastics 21 (1944) 121.

    Google Scholar 

  30. A. J. Kinloch and R. J. Young, “Fracture behaviour of polymers” (Applied Science, London, 1983).

    Google Scholar 

  31. C. B. Bucknall, D. Clayton and W. E. Keast, J. Mater. Sci. 7 (1972) 1443.

    Article  CAS  Google Scholar 

  32. P. M. Croes, F. H. C. Edgecombe and P. Jeffrey in Proceedings of 7th annual SEM symposia, Part IV (Illinois, 1974).

  33. “Processing structure and properties of block polymers”, edited by M. J. Folker (Elsevier, Amsterdam, 1985).

    Google Scholar 

  34. Voyutski, in “Autofusion and adhesion of high polymers”, edited by Vakula (Interscience, New York, 1963).

    Google Scholar 

  35. “Mechanical properties of polymers”, edited by N. M. Bikales (Wiley Interscience, New York, 1969).

    Google Scholar 

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Somanathan, N., Sanjeevi, R. Fracture behaviour of casein films — II. JOURNAL OF MATERIALS SCIENCE 29, 3553–3558 (1994). https://doi.org/10.1007/BF00352062

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