Abstract
Minnesotaite, a 2:1 layer sheet silicate, is antifer-romagnetic below 30 K. A spin flop or metamagnetic transition occurs in a small applied magnetic field. Neutron diffraction and Mössbauer spectroscopy, in an external magnetic field of 4.0 T, show that the magnetic structure consists of Fe2+ spins coupled ferromagnetically in the c plane with alternate ferromagnetic planes coupled antiferromagnetically.
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Townsend, M.G., Longworth, G. & Roudaut, E. Field-induced ferromagnetism in minnesotaite. Phys Chem Minerals 12, 9–12 (1985). https://doi.org/10.1007/BF00348739
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DOI: https://doi.org/10.1007/BF00348739