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Reactions of organoboron polymers prepared by hydroboration polymerization

II. Selective synthesis of poly(ketone) by the reaction with cyanide anion

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Summary

This paper describes a novel methodology for the preparation of poly(ketone). An organoboron polymer was prepared by polyaddition between thexylborane and 1,7-octadiene, which was reacted with potassium cyanide in the presence of trifluoroacetic anhydride. After oxidation of the reaction mixture, the corresponding poly(ketone) was obtained.

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Authors and Affiliations

  1. Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo-ku, 606, Kyoto, Japan

    Yoshiki Chujo, Ikuyoshi Tomita, Yuichi Hashiguchi & Takeo Saegusa

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  1. Yoshiki Chujo
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  2. Ikuyoshi Tomita
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  3. Yuichi Hashiguchi
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  4. Takeo Saegusa
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Chujo, Y., Tomita, I., Hashiguchi, Y. et al. Reactions of organoboron polymers prepared by hydroboration polymerization. Polymer Bulletin 25, 1–4 (1991). https://doi.org/10.1007/BF00338891

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  • DOI: https://doi.org/10.1007/BF00338891

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