Abstract
A highly conductive gold film, over 10 μm-thick with well-controlled linewidth, has been successfully deposited from dimethyl-gold-acetylacetonate and its fluorinated derivative by pyrolytic CVD (Chemical Vapor Deposition) with a high-repetition, visible, pulsed laser. The thermal damage to the polyimide substrate has been substantially suppressed by reducing the thermal diffusion length within 0.2 μm in pulsed-laser-induced transient heating, in contrast to the cw laser-CVD scheme. Reproducible and low contact resistance as low as 0.5 Ω between the written line and the existing gold line has been obtained. Sufficiently tough adhesion to polyimide has been observed for the deposit from dimethyl-gold-acetylacetonate. Reasonable agreement has been obtained between the observed deposition characteristics and analytical results for precursor supply rate and temperature increase during short-pulse irradiation.
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References
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