Skip to main content
Log in

Measurements of hydrogen peroxide in Antarctic ambient air, snow and firn cores

  • Original Papers
  • Environmental Analysis
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Summary

First measurements of H2O2 at a coastal Antarctic station (Georg von Neumayer) during summer 89/90 indicated mean gas phase concentrations of 0.4 ppbv. Concentration variations of gaseous H2O2 were not significantly related to a diurnal pattern, but to evaporation and recrystallisation processes of H2O2 in snow and hoarfrost. H2O2 concentrations in snow — ranging from 90 to 480 ppbw — decreased after deposition, and no distinct seasonal structure could be found in pit studies and firn core analyses down to 12 m depth.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Neftel A, Jacob P, Klockow D (1984) Nature 311:43–45

    Google Scholar 

  2. Neftel A, Jacob P, Klockow D (1986) Tellus 38B:262–270

    Google Scholar 

  3. Stauffer BR, Neftel A (1986) In: Rowland FS, Isaksen ISA (eds) The changing atmosphere. Wiley, Chichester, New York, pp 63–77

    Google Scholar 

  4. Delmas RJ (1992) Rev Geophys 30:1–21

    Google Scholar 

  5. Isaksen ISA (1986) In: Rowland FS, Isaksen ISA (eds) The changing atmosphere. Wiley, Chichester, New York, pp 141–157

    Google Scholar 

  6. Sigg A, Neftel A (1991) Nature 351:557–559

    Google Scholar 

  7. Sigg A (1990) PhD Thesis, Bern

  8. Sigg A, Staffelbach T, Neftel A (1992) J Atmos Chem 14:223–232

    Google Scholar 

  9. Jacob P (1987) PhD Thesis, Dortmund

  10. Thompson AM, Owens MA, Stewart RW (1989) Geophys Res Lett 16:53–56

    Google Scholar 

  11. Neubauer J (1988) PhD Thesis, Regensburg

  12. Jacob P, Tavares TM, Klockow D (1986) Fresenius Z Anal Chem 325:359–364

    Google Scholar 

  13. Jacob P, Tavares TM, Rocha VC, Klockow D (1990) Atmos Environ 24A:377–382

    Google Scholar 

  14. Ross HB, Johansson C, de Serves C, Lind J (1992) J Atmos Chem 14:411–423

    Google Scholar 

  15. Klockow D, Jacob P (1986) In: Jaeschke W (ed) Chemistry of Multiphase Atmospheric Systems. Springer, Berlin Heidelberg New York, pp 117–130

    Google Scholar 

  16. Jacob P, Klockow D (1992) J Atmos Chem 15:353–360

    Google Scholar 

  17. Pfaff K, PhD Thesis, Innsbruck (in preparation)

  18. Wittenzeller J (1990) Diploma Thesis, Regensburg

  19. Herron MM, Langway Jr CC (1985) In: Langway Jr CC, Oeschger H, Dansgaard W (eds) Greenland Ice Core: Geophysics, geochemistry and the environment, Washington DC, pp 77–84

  20. Beer J, Finkel RC, Neftel A, Oeschger H, Schotterer U, Schwander J, Siegenthaler U, Bonani C, Suter M, Wölfli W, Langway Jr CC, Jacob P, Klockow D, Gäggeler H, Wagenbach D (1990) Atmos Environ 25:899–904

    Google Scholar 

  21. Neubauer J, Heumann KG (1988) Atmos Environ 22:537–545

    Google Scholar 

  22. Neubauer J, Heumann KG (1988) Fresenius Z Anal Chem 331:170–173

    Google Scholar 

  23. Nishio F, personal communication

  24. Wagner V, Seewetteramt Hamburg, personal communication

Download references

Author information

Authors and Affiliations

Authors

Additional information

Dedicated to Professor Dr. V. Krivan on the occasion of his 60th birthday

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jacob, P., Klockow, D. Measurements of hydrogen peroxide in Antarctic ambient air, snow and firn cores. Fresenius J Anal Chem 346, 429–434 (1993). https://doi.org/10.1007/BF00325856

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00325856

Keywords

Navigation