Skip to main content
SpringerLink
Log in

Determination of thermolabile urea pesticides after derivatization with HFBA using GC-ECD and confirmation by means of GC-MSD

  • Original Papers
  • Residue Analyses
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Summary

The determination of urea pesticides is difficult by means of gas chromatography because they undergo thermal decomposition when applying standardized chromatographic conditions as used in multiresidue analysis. A method is therefore described to make possible the detection of these compounds by gas chromatography after derivatization with HFBA using either electron capture and nitrogen-phosphorus detection or a mass spectrometer as detector.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Spengler D, Hamroll B (1970) J Chromatogr 49:205–214

    Google Scholar 

  2. Tanaka FS, Wien RG (1973) J Chromatogr 87:85–93

    Google Scholar 

  3. Saunders DG, Vanatta LE (1974) Anal Chem 46:1319–1321

    Google Scholar 

  4. Glad DG, Popoff Th, Theander O (1978) J Chromatogr Sci 16:118–122

    Google Scholar 

  5. Muszkat L, Aharonson N (1986) In: Zweig G, Sherma J (eds) Analytical methods for pesticides and plant growth regulators, vol XIV. Academic Press, Orlando, Florida, p 95–132

    Google Scholar 

  6. Moye HA (1981) In: Moye HA (ed) Analysis of pesticide residues, chemical analysis series, vol 58. Wiley, New York, p 157–198

    Google Scholar 

  7. Tamini T, Zitrin S (1987) Biomed Mass Spectrom 14:39–42

    Google Scholar 

  8. Perez S, Garcia-Baudi JM, Tadeo JL (1990) In: Frehse H, Kesseler-Schmitz E, Conway S (eds) Book of abstracts — Seventh International Congress of Pesticide Chemistry, vol 3

  9. Moffat AC, Horning EC, Martin SB, Rowland M (1972) J Chromatogr 66:255–260

    Google Scholar 

  10. Bradway DE, Shafik TJ (1977) Chromatogr Sci 15:322–328

    Google Scholar 

  11. Zeman A, Mirotama IPG (1969) Fresenius Z Anal Chem 247:158–163

    Google Scholar 

  12. Müller H-M (1989) Thesis, Technical University Berlin (FRG)

  13. Brinkman UATh, de Kok A, Geerdink RB (1984) J Chromatogr 283:113–126

    Google Scholar 

  14. de Milo AB, Terry PH, Rains DM (1976) J Assoc Off Anal Chem 61:629–635

    Google Scholar 

  15. Homberg AH, Heinrichs LC, Barringer VM. Tin M, Gentry GA (1977) J Assoc Off Anal Chem 60:716–719

    Google Scholar 

  16. Ryan JJ, Lawrence JF (1977) J Chromatogr 135:117–122

    Google Scholar 

  17. Knapp DR (1979) Handbook of analytical derivatization reactions. Wiley, New York

    Google Scholar 

  18. Bose JR (1977) J Agric Food Chem 25:1209–1210

    Google Scholar 

  19. Woroby BC, Webster GRB (1977) J Assoc Off Anal Chem 60:986

    Google Scholar 

  20. S19 DFG Pesticide Commission (1987) Manual of pesticide residue analysis. VCH, Weinheim

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Food Chemistry, Technical University of Berlin, Gustav-Meyer-Allee 25, W-1000, Berlin 65, Germany

    H.-J. Stan & P. Klaffenbach

Authors
  1. H.-J. Stan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Klaffenbach
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stan, HJ., Klaffenbach, P. Determination of thermolabile urea pesticides after derivatization with HFBA using GC-ECD and confirmation by means of GC-MSD. Fresenius J Anal Chem 339, 40–45 (1991). https://doi.org/10.1007/BF00324757

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00324757

Keywords

Search

Navigation