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Model of laser-induced chemical etching of silicon in chlorine atmosphere

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Abstract

A mathematical model for the chemical etching of silicon in a chlorine atmosphere induced by laser irradiation is described. The model takes into account: dissociation of molecules having absorbed radiant energy into chlorine atoms and their diffusion onto the substrate surface, generation of photocarriers in the silicon substrate, kinetics of chlorine atom chemisorption on the silicon surface, chemical reaction of chemisorbed chlorine atoms with silicon atoms, and desorption of reaction products. The obtained results are compared with experimental data.

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References

  1. T.J. Chuang: Mater. Res. Soc. Symp. Proc. 29, 185 (1984)

    Google Scholar 

  2. D.J. Ehrlich, R.M. Osgood, Jr., T.F. Deutsch: Appl. Phys. Lett. 38, 1018 (1981)

    Google Scholar 

  3. P. Mogyorósi, K. Piglmayer, R. Kullmer, D. Bäuerle: Appl. Phys. A 45, 293 (1988)

    Google Scholar 

  4. R. Kullmer, D. Bäuerle: Appl. Phys. A 47, 377 (1988)

    Google Scholar 

  5. R. Kullmer, D. Bäuerle: Appl. Phys. A 43, 227 (1987)

    Google Scholar 

  6. H. Okano, Y. Horiike, M. Sekine: Jpn. J. Appl. Phys. Pt. 1, 24, 68 (1985)

    Google Scholar 

  7. Y. Horiike, M. Sekine, K. Horioka, T. Arikado, H. Okano: Extended Abstr. 16 Int'l Conf. Solid State Dev. and Mater., Kobe (1984) p. 441

  8. T. Arikado, M. Sekine, H. Okano: Mater. Res. Soc. Symp. Proc. 29, 167 (1984)

    Google Scholar 

  9. P.K. Larsen, N.V. Smith, M. Schluter, H.H. Farrell, K.N. Ho, M.L. Cohen: Phys. Rev. B 17, 2612 (1978)

    Google Scholar 

  10. G.E. Jellison, F.A. Modine: Phys. Rev. B 27, 7466 (1983)

    Google Scholar 

  11. J.G. Calvert, J.N. Pitts, Jr.: Photochemistry (Wiley, New York 1966)

    Google Scholar 

  12. H. Okabe: Photochemistry of Small Molecules (Wiley, New York 1978)

    Google Scholar 

  13. Th. Wolkenstein: Electron Processes on a Semiconductor Surface During Chemisorption (Nauka, Moscow 1987)

    Google Scholar 

  14. B.M.W. Trapnell: Chemisorption (Butterworths, London 1955)

    Google Scholar 

  15. H. Eyring, S.H. Lin, S.M. Lin: Basic chemical kinetics (Wiley, New York 1980)

    Google Scholar 

  16. G.E. Jellison, F.A. Modine: Appl. Phys. Lett. 41, 180 (1982)

    Google Scholar 

  17. J. Auth, D. Genzow, K.H. Herrmann: Photoelektrische Erscheinungen (Akademie-Verlag, Berlin 1977)

    Google Scholar 

  18. J. Dziewior, W. Schmid: Appl. Phys. Lett. 31, 346 (1977)

    Google Scholar 

  19. T. Baller, D.J. Oostra, A.E. de Vries, G.N.A. van Veen: J. Appl. Phys. 60, 2321 (1986)

    Google Scholar 

  20. O.C. Zienkiewicz, K. Morgan: Finite Elements and Approximation (Wiley, New York 1983)

    Google Scholar 

  21. L.J. Segerlind: Applied Finite Element Analysis (Wiley, New York 1976)

    Google Scholar 

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Sytov, I.P. Model of laser-induced chemical etching of silicon in chlorine atmosphere. Appl. Phys. A 55, 372–377 (1992). https://doi.org/10.1007/BF00324087

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  • DOI: https://doi.org/10.1007/BF00324087

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