Abstract
The direct determination of traces of certain heavy metals in oils is possible after treatment of the methanolic sample solution with Lumatom (tetramethylammoniumhydroxide). For the inverse voltammetric determination, a flow through cell with a mercury film electrode is used. The results for the determination of Cu and Pb in some edible oils after solubilization agree well with those obtained using wet oxidative high pressure ashing.
References
Alt F, Massmann H (1987) Spectrochim Acta 338:337–342
Julshamn K, Andersen KJ (1979) Anal Biochem 98:315–318
Nembrini PG, Dogan S, Haerdi W (1980) Anal Letters 13:947–957
Uchida T, Isoyama H, Yamada K, Oguchi K, Nakagawa G (1992) Anal Chim Acta 256:227–284
Rozali M, Othman B, Hill JO, Magec RJ (1987) Fresenius Z Anal Chem 326:350–353
Wahdat F, Lukaszewski Z, Neeb R (1990) Fresenius J Anal Chem 338:163–167
Elworthy PH, Florena AT, Maefarlane CB (1968) In: Solubilization by surface active agents. Chapman and Hall, London
Eicke H-F (1980) Top Curr Chem 87:138–146
Bowcott JE, Schulman JH (1955) Z Elektrochem 59:283
Prince LM (1975) J Coll Interface Sci 52:182
Eicke H-F (1976) J Coll Interface Sci 59:308
Kirchhoff JR, Deutsch E, Heineman WR (1989) Anal Letters 22:1323–1340
Kirchhoff JR, Heineman WR, Deutsch E (1988) Inorg Chem 27:3608–3614
Yeh P, Kuwana T (1976) J Electrochem Soc 123:1334–1339
Ohsawa Y, Aoyagui S (1982) J Electroanal Chem 136:353–360
Wahdat F, Neeb R (1987) Fresenius Z Anal Chem 327:175–178
Wahdat F, Neeb R (1995) Fresenius J Anal Chem (in press)
Saur D, Spahn E (1995) Fresenius J Anal Chem (in press)
Knapp C (1984) Fresenius Z Anal Chem 317:240
Wahdat F, Neeb R (1995) Fresenius J Anal Chem (in preparation)
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Wahdat, F., Hinkel, S. & Neeb, R. Direct inverse voltammetric determination of Pb, Cu and Cd in some edible oils after solubilization. Fresenius J Anal Chem 352, 393–394 (1995). https://doi.org/10.1007/BF00322240
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DOI: https://doi.org/10.1007/BF00322240