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Spectrophotometric determination of manganese in low-alloy steels after its extraction as triphenylsulphonium permanganate

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  • General And Inorganic Chemistry
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Summary

Manganese(VII) (0–100 μg) can be determined spectrophotometrically at 548 nm after its extraction as triphenylsulphonium permanganate into chloroform. The effects of pH, reagent conditions and diverse ions are reported. The system has been applied to the determination of manganese in a range of steels. For the determination of 60 μg of manganese the relative standard deviation was 0.5% (n=7).

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References

  1. Keller WE (1979) Compendium of phase-transfer reactions and related synthetic methods, Fluka, Buchs, Switzerland

    Google Scholar 

  2. Courtot C, Tung TY (1933) Compt Rend 1226

  3. Katsutoshi O, Tokio Y, Fukui K (1969) Bull Chem Soc Jpn, 42:1800

    Google Scholar 

  4. Fukui K, Kanai K, Takezono T, Kitana H (1964) Kogyo Kagaku Zasshi 67:1131

    Google Scholar 

  5. Kanai K, Okubo K, Katano H, Fukui K (1965) Bull Jpn Pet Inst 7:52

    Google Scholar 

  6. Abrahams IM, Benezra LL, Goold RD (1962) US Patent 3, 028-361, April 3 1962, Chem Abstr 57:2411f.

  7. Antognini J, Curtis R, Day HM (1958) Symposium on metal chelates in plant nutrition (Seattle 1956), p 61; Chem Abstr 52:5565f.

  8. Pugh AL, Vomocil JA, Nielson TR (1960) Agron J 52:399

    Google Scholar 

  9. Potratz HA, Rosen JM (1949) Anal Chem 21:1276

    Google Scholar 

  10. Thorburn Burns D, Kheawpintong S (1984) Anal Chim Acta 162:437

    Google Scholar 

  11. Shinagawa M, Matsuo H, Maki N (1956) Jpn Anal 5:80

    Google Scholar 

  12. Williams WJ (1979) Handbook of Anion Determination, London, p 163

  13. Job P (1928) Ann Chim 9:113

    Google Scholar 

  14. Thorburn Burns D, Chimpalee D (1987) Anal Chim Acta 199:241

    Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, The Queen's University of Belfast, BT9 5AG, Belfast, Northern Ireland

    D. Thorburn Burns, M. Harriott & S. A. Barakat

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  1. D. Thorburn Burns
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  2. M. Harriott
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  3. S. A. Barakat
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Burns, D.T., Harriott, M. & Barakat, S.A. Spectrophotometric determination of manganese in low-alloy steels after its extraction as triphenylsulphonium permanganate. Fresenius J Anal Chem 343, 488–490 (1992). https://doi.org/10.1007/BF00322155

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  • DOI: https://doi.org/10.1007/BF00322155

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