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Syntheses of mono(1,3-oxazolin-2-yl)-terminated oligopropene macromonomers and novel polymers containing oligopropene side chains

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Summary

Mono(1,3-oxazolin-2-yl)-terminated atactic oligopropene with Mn=710g/mol was derived in high yields from monoester-terminated oligopropene via reaction with 2-aminoethanol and subsequent Ti(OC4H9)4-catalyzed dehydration at 180°C. Cationic bulk polymerization of this novel macromonomer, initiated with 2 mol% methyl-4-nitrobenzenesulfonate at 200°C, afforded high molecular weight poly[N-oligopropene-1-carbonyl]-ethyleneimine]. Grafting of mono(1,3-oxazolin-2-yl)-terminated oligopropene with poly(ethene-co-methacrylic acid), containing 3 mol% methacrylic acid, by heating both components for 15minutes at 220°C yielded novel ethene copolymers containing 41wt% esteramide-coupled oligopropene as side chains.

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Authors and Affiliations

  1. Freiburger Materialforschungszentrum und Institut für Makromolekulare Chemie der Albert-Ludwigs-Universität, Stefan-Meier-Str. 21, D-79104, Freiburg i. Br., Germany

    Christof Wörner & Rolf Mülhaupt

  2. BASF AG, D-67056, Ludwigshafen, Germany

    Joachim Rösch & Arthur Höhn

Authors
  1. Christof Wörner
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  2. Joachim Rösch
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  3. Arthur Höhn
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  4. Rolf Mülhaupt
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Wörner, C., Rösch, J., Höhn, A. et al. Syntheses of mono(1,3-oxazolin-2-yl)-terminated oligopropene macromonomers and novel polymers containing oligopropene side chains. Polymer Bulletin 36, 303–309 (1996). https://doi.org/10.1007/BF00319229

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  • DOI: https://doi.org/10.1007/BF00319229

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