Summary
The viscoelastic properties of polyacrylamide/Cr(III) hydrogels were characterized with the help of oscillatory shear rheometer. The serrated-plate geometry rather than the cone-plate geometry was used in order to avoid the slip effect. The dynamic storage modulus (G') increased with increasing polyacrylamide and/or Cr(III) concentrations. The mean molecular weight of the chains adjoining adjacent crosslinks (Mc), calculated according to the elastic rubber theory, exhibited the same order of the primary polymer. G' decreased with increasing monovalent salt concentration, owing to the polyelectrolyte effect.
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References
Mumallah NA (1988) Soc. Pet. Eng. Reservoir Eng., 2: 243
Sydansk RD (1990) Soc. Pet. Eng. Reservoir Eng., 8: 346
Lockhart TP, Albonco P, Burrafato G (1991) J. Appl. Polym. Sci., 17: 659
Ferry JD (1970) Viscoelastic Properties of Polymers, 2nd ed., Wiley & Sons, New York
Han M, Shi L, Ye M, Ma J (1995) Polym. Bulletin, 35: 109
Han M, Shi L, Ye M, Muller G (1996) Chinese J Polym. Sci., 14(1): 65
Moradi-Araghi A, Beardmore DH, Stahl GA (1988) in Water-Soluble Polymers for Petroleum Recovery, Plenum Press, New York, 299
Prud'homme RK, Uhl JT (1984) Soc. Pet. Eng. Paper 12640, the SPE/DOE 4th Symp. on Enhanced Oil Recovery, Tulsa, OK, April 15–18
Gallino G, Molinari M, Lockhart TP (1991) Makromol. Chem., Macromol. Symp., 45: 137
Lund T, Smidsrod O, Stokke BT, Elgsaeter A (1988) Carbohydrate Polym., 8:245
Treloar LRG (1975) The Physics of Rubber Elasticity, Clarendon Press, Oxford
Muller G, Laine JP, Fenyo JC (1979) J. Polym. Sci., Polym. Chem. Ed., 17:659
Yuan DW, Zhu SN, Yang XZ (1987) Oilfield Chemistry, 4(1): 44
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Han, M., Shi, L., Ye, M. et al. Characterization of viscoelastic properties of polyacrylamide/Cr(III) hydrogels. Polymer Bulletin 36, 483–487 (1996). https://doi.org/10.1007/BF00315067
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DOI: https://doi.org/10.1007/BF00315067