Summary
The copolymerization of N-(2-hydroxyethyl)ethyleneimine, (HEEI) as nucleophilic monomer and maleic anhydride (MA) as electrophilic monomer in the absence of initiator in acetonitrile was investigated. Copolymers were characterized by IR, 1H-NMR and 13C-NMR spectroscopy. The copolymer composition depends on the monomer ratio in the feed, determined by 1H-NMR spectroscopy. The presence of MA bridges between copolymer chains was established by spectroscopic analysis. At lower temperature the yield and molecular weight of copolymers decrease as well as the MA unit content in the copolymer.
Similar content being viewed by others
References
T. Saegusa, S. Kobayashi, Y. Kimura. Pure Appl. Chem., 48, 307 (1976).
T. Saegusa. Chemtech., 5, 295 (1975).
T. Saegusa, S. Kobayashi. Pure Appl. Chem., 50, 281 (1978).
T. Saegusa, H. Ikeda, H. Fujii. Macromolecules, 5, 354 (1972).
T. Saegusa, S. Kobayashi, Y. Kimura. Macromolecules, 7, 139 (1974).
T. Balakrishnan, M. Periyasamy. Polymer, 23, 1372 (1982).
G. Odian, P.A. Gunatillake. Macromolecules, 17, 1297 (1984).
C.I. Simionescu, M. Grigoras, E. Bicu, G. Onofrei. Polym. Bull., 14, 79 (1985).
B.L. Rivas, S.A. Pooley. An. Quím., 79, 62 (1983).
B.L. Rivas, G.S. Canessa, S.A. Pooley. Polym. Bull., 13, 65 (1985).
B.L. Rivas, G.S. Canessa, S.A. Pooley. Eur. Polym. J., 21, 939 (1985).
B.L. Rivas, G.S. Canessa, S.A. Pooley. Makromol. Chem., 187, 71 (1986).
B.L. Rivas, G.S. Canessa, S.A. Pooley, Makromol. Chem., 188, 149 (1987).
B.L. Rivas, G.S. Canessa, S.A. Pooley. Makromol. Chem Rapid Commun., 8, 365 (1987).
B.L. Rivas, G.S. Canessa, S.A. Pooley. Makromol. Chem., 190, 2665 (1989).
B.L. Rivas, G.S. Canessa, S.A. Pooley Eur. Polym. J., 25, 225 (1989).
B.L. Rivas, G.S. Canessa, S.A. Pooley. Eur. Polym. J., 28, 43 (1992).
S.A. Pooley, G.S. Canessa, B.L. Rivas. Eur. Polym. J., 29, 1239 (1993).
S.A. Pooley, G.S. Canessa, B.L. Rivas, E. Espejo. Bol. Soc. Chil. Quím., 39, 305 (1994).
S.A. Pooley, G.S. Canessa, B.L. Rivas. Eur. Polym. J., 31, 547 (1995).
W.Y. Wen, J.W. Lin. J. Appl. Polym. Sci., 22, 228 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pooley, S.A., Canessa, G.S., Rivas, B.L. et al. Spontaneous copolymerization of N-(2-hydroxyethyl)ethyleneimine with maleic anhydride. Polymer Bulletin 36, 415–422 (1996). https://doi.org/10.1007/BF00315057
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00315057