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Synthesis and properties of poly(dipropargyl-16-crown-5)

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Summary

We have synthesized a polyacetylene derivative, poly(dipropargyl-16-crown-5), through the cyclopolymerization of the corresponding monomer by metathesis catalysts. The polymer containing crown-ether units was characterized by spectroscopic and thermal techniques. The polymer structure is believed to be a cyclized from with both five- and sixmembered rings. The polymer exhibits high cation-binding properties and ionochromic effects. The order of the selectivity of alkali- metal cations for both the monomer and the polymer was found to be Na+>K+>Li+ and the polymer shows the largest red shift by approximately 40 nm in λmax for Na+.

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Authors and Affiliations

  1. Polymer Materials Laboratory, Korea Institute of Science and Technology, Cheongryang, P.O. Box 131, Seoul, Korea

    H. N. Cho, J. Y. Lee & C. Y. Kim

  2. Department of Chemistry, Korea Advanced Institute of Science and Technology, 373-1 Kusung-Dong, Yusung-Gu, Daejon, Korea

    S. H. Kim & S. K. Choi

Authors
  1. H. N. Cho
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  2. J. Y. Lee
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  3. S. H. Kim
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  4. S. K. Choi
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  5. C. Y. Kim
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Cho, H.N., Lee, J.Y., Kim, S.H. et al. Synthesis and properties of poly(dipropargyl-16-crown-5). Polymer Bulletin 36, 391–398 (1996). https://doi.org/10.1007/BF00315054

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  • DOI: https://doi.org/10.1007/BF00315054

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