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Stereoregular polymerization of polysiobutylene macromonomer having methacryloyl function

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Summary

The polysiobutylene (PIB) macromonomer having methacryloyl function was prepared from a hydroxy-terminated PIB, α-phenyl-ω-(2-hydroxy-1-methylethyl)-poly(1,1-dimethylethylene) and methacryloyl chloride in the presence of triethylamine. The macromonomer was polymerized by various anionic initiators to form stereoregular polymacromonomers. The polymerization of the macromonomer with t-C4H9MgBr and n-C4H9Li in toluene gave isotactic polymacromonomers. On the other hand, syndiotactic-rich polymacromonomers were obtained in the polymerizations with 1,1-diphenylhexyllithium in tetrahydrofuran and with t-C4H9Li/(C2H5)3Al in toluene.

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References

  1. Hatada K, Nakanishi H, Ute K, Kitayama T (1986) Polym J 18: 581

    Google Scholar 

  2. Hatada K, Shinozaki T, Ute K, Kitayama T (1988) Polym Bull 19: 231

    Google Scholar 

  3. Hatada K, Kitayama T, Ute K, Masuda E, Shionozaki T, Yamamoto M (1989) Polym Bull 21: 165

    Google Scholar 

  4. Hatada K, Kitayama T, Masuda E, Kamachi M (1990) Makromol Chem Rapid Commun 11: 101

    Google Scholar 

  5. Hatada K, Kitayama T, Ute K (1989) Prog Polym Sci 13: 189

    Google Scholar 

  6. Masson P, Franta E, Rempp P (1982) Makromol Chem Rapid Commun 3: 499

    Google Scholar 

  7. Asami R, Kyuda K, Takaki M, Ogawa Y (1982) Polym Prepr Jpn 31: 277

    Google Scholar 

  8. Kennedy J P, Hiza M (1983) Polym Bull 10: 146

    Google Scholar 

  9. Hatada K, Ute K, Tanaka K, Okamoto Y, Kitayama T (1986) Polym J 18: 1037

    Google Scholar 

  10. Kitayama T, Shinozaki T, Sakamoto T, Yamamoto M, Hatada K (1989) Makromol Chem Supplement 15: 167

    Google Scholar 

  11. Anderson B C, Amdrews G D, Arthur Jr P, Jacobson H W, Playtis A J, Sharkey W H (1981) Macromolecules 14: 1599

    Google Scholar 

  12. Das R K, Allen R D, Ward T C, McGrath J E, Dodson R J (1984) Polym Prep Am Chem Soc; Div Polym Chem 25(1): 185

    Google Scholar 

  13. Lutz P, Masson P, Beinert G, Rempp P (1984) Polym. Bull. 12: 79

    Google Scholar 

  14. Cao Z-K, Okamoto Y, Hatada K (1986) Kobunshi Ronbunshu 43: 857

    Google Scholar 

  15. Hatada K, Kitayama T, Fujikawa K, Ohta K, Yuki H (1981) Anionic Polymerization; Kinetics, Mechanism, and Synthesis (J.E. McGrath Ed.), ACS Symposium Series 166: 327

  16. Hatada K, Kitayama T, Okahata S, Yuki H (1981) Polym J 13: 1045

    Google Scholar 

  17. Hatada K, Kitayama T, Okahata S, Yuki H (1982) Polym J 14: 971

    Google Scholar 

  18. Ute K, Kitayama T, Hatada K (1986) Polym J 18: 249

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Engineering Science, Osaka University, 560, Toyonaka, Osaka, Japan

    Tatsuki Kitayama, Shigeki Kishiro & Koichi Hatada

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  1. Tatsuki Kitayama
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  2. Shigeki Kishiro
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  3. Koichi Hatada
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Kitayama, T., Kishiro, S. & Hatada, K. Stereoregular polymerization of polysiobutylene macromonomer having methacryloyl function. Polymer Bulletin 25, 161–168 (1991). https://doi.org/10.1007/BF00310787

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  • DOI: https://doi.org/10.1007/BF00310787

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