Summary
The model compound 1,4-bis(anisylimido)benzene has been characterized by solution and CP/MAS 13C NMR to assist in the characterization of liquid crystalline polyazomethines (PAM) based on the same mesogenic structure. Thermal behavior of several homologs of this PAM series have been compared before and after treatment with the end capping agent benzaldehyde. The results suggest that PAM oligomers containing large quantities of amine termination can strongly effect thermal behavior at constant oligomer molecular weight.
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Shaffer, T.D., Shaffer, M.L. The influence of H-bonding in liquid crystalline polyazomethine ethers. Polymer Bulletin 27, 429–434 (1992). https://doi.org/10.1007/BF00309701
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DOI: https://doi.org/10.1007/BF00309701