Skip to main content
Log in

The influence of H-bonding in liquid crystalline polyazomethine ethers

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The model compound 1,4-bis(anisylimido)benzene has been characterized by solution and CP/MAS 13C NMR to assist in the characterization of liquid crystalline polyazomethines (PAM) based on the same mesogenic structure. Thermal behavior of several homologs of this PAM series have been compared before and after treatment with the end capping agent benzaldehyde. The results suggest that PAM oligomers containing large quantities of amine termination can strongly effect thermal behavior at constant oligomer molecular weight.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kato T, Fujishima A, Uryu T, Matsushita N, Hiromichi Y, (1990) New Polym Mat 2: 255

    Google Scholar 

  2. Kato T, Kabir GMA, Uryu T, (1989) J Polym Sci Polym Chem Ed 27: 1447

    Google Scholar 

  3. Kato T, Uryu T (1987) Mol Cryst Liq Cryst 5: 17

    Google Scholar 

  4. Volksen W, Lyeria JR, Economy J, Dawson B, (1983) J Polym Sci Polym Chem Ed 21: 2249

    Google Scholar 

  5. Wojtkowski PW, (1987) Macromolecules 20: 740

    Google Scholar 

  6. Lupinacci, (1984) Eur Polym J 20: 73

    Google Scholar 

  7. Griffin AC, Britt TR, Hung RS, Steele ML, (1984) Mol Cryst Liq Cryst 105: 305

    Google Scholar 

  8. Deschenaux R, Neuenschwander P, Pino P, (1986) Helv Chim Acta 69: 1349

    Google Scholar 

  9. Millaud B, Thierry A, Strazielle C, Skoulious A, (1979) Mol Cryst Liq Cryst 49: 299

    Google Scholar 

  10. Guillon D, Skulios A, (1978) Mol Cryst Liq Cryst 49: 11

    Google Scholar 

  11. Shaffer TD, Percec V, (1985) Makromol Chem Rapid Comm 6: 97

    Google Scholar 

  12. Shaffer TD, Shaffer ML, J Polym Sci Polym Chem Ed submitted

  13. Fyfe CA, (1983) Solid State NMR for Chemists. CFC Press, Guelph

    Google Scholar 

  14. Opella SJ, Frey DMH, (1979) J Amer Chem Soc 101: 5855

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shaffer, T.D., Shaffer, M.L. The influence of H-bonding in liquid crystalline polyazomethine ethers. Polymer Bulletin 27, 429–434 (1992). https://doi.org/10.1007/BF00309701

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00309701

Keywords

Navigation