Abstract
The shock-metamorphosed quartz exhibits thermal luminescence (TL) with maxima at 365 nm, 470 nm and 610–680 nm. By electron paramagnetic resonance (EPR) analysis E1 type electron centers and hole centers have been found which originate from vacancies including those from the substitution of Al3+ and/or Fe3+, for Si4+. The EPR and TL spectra may be interpreted mainly in terms of vacancy type defects associated with dislocations in the crystal structure of quartz.
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References
Anuphrienko VF, Yandralova LG, Tarasova DV (1971) EPR spectra and Fe3+ ions state in SnO2 (in Russian). Physica Tverdogo Tela 13:N8, 2353–2356
Batrak EN (1958) Temperature glow and decoloration of the X-ray irradiated quartz crystals (in Russian). Crystallography 3:N5, 627–629
Batsanov SS (1972) Syntheses under the action of shock pressure. In: Hagenmuller P (ed) Preparative methods in solid state chemistry. Academic Press, New York London, pp 157–170
Batsanov SS (1978) Chemical reactions under the shock wave pressure. In: Dubvitsky FJ (ed) Detonation. Kinetic phenomena. Physical-chemical transformation in shock waves (in Russian). Acad Sci USSR, Dept of Chem Phys, Chernogolovka, pp 126–131
Bershov LV, Marfunin AS, Speranskii AV (1978) The new stable electronic center in quartz (in Russian). Izv Acad Nauk SSSR Ser Geol N 11, 106–116
Christie JM, Griggs DT, Carter NL (1964) Experimental evidence of basal slip in quartz. J Geol 72:734–756
Horz F, Quaide WL (1973) Debye-Sherrer investigations of experimentally shocked silicates. Moon 6:45–82
Lisakov VS, Serebrennikov AI, Solntsev VP (1969) On the centers and thermoluminescence spectra of natural and synthetic quartz (in Russian) J. Prikl Spectr 11:757–760
Luschik CB (1955) Investigation of capture centers in alkali-haloid phosphor crystals (in Russian). Tr Inst Phys Astron Est SSR 3:
Marfunin AS (1979) Spectroscopy, luminescence and radiation centers in minerals. Springer, Berlin Heidelberg New York
Mashkovtsev RI, Scherbakova MYa, Solntsev VP (1978) EPR of radiation hole centers in α-quartz (in Russian). In: Sobolev VS (ed) Rentgenographia i spectroscopia mineralov. Nauka, Novosibirsk pp 78–86
Mashkovtsev RI, Solntsev VP, Scherbakova MYa (1977) Electronic paramagnetic centers with s=I in quartz. Abstracts. IV International Symposium of Magnetic Resonance, Alberta, Canada
Maslova GA, Samoilovich MI (1978) On the “memory” effect of the preliminary irradiation by the study of quartz thermoluminescence. In: H'utt GJ (ed) The use of investigation results of mineral luminescence in geology (in Russian). Inst Geol Acad Sci Est SSR, Tallin, pp 64–67
O'Brien MC (1955) The structure of the color centers in smoky quartz. Proc Roy Soc London Ser A231:404–415
Schnadt R, Schneider J (1970) The electron structure of the trapped-Hole center in smoky quartz. Phys Kondens Mater 11:19–42
Schnadt R, Rauber A (1971) Motional effects in trapped-hole center in smoky quartz. Solid State Commun 9:159–161
Serebrennikov AI (1974) Thermoluminescence of quartz subjected to electrolysis in air and vacuum. In: Semenenko NP (ed) The questions of geochemistry, mineralogy, petrology and ore forming (in Russian). Naukova Dumka, Kiev, pp 54–58
Serebrennikov AI (1978) Experimental investigation of electronhole centers in quartz. II. Emission centers (in Russian). Mineral Sb (Lvov) 32:15–20
Silsbee RH (1961) Electron spin resonance in neutron-irradiated quartz. J Appl Phys 32:1459–1462
Smolianskii PL, Masaitis VL (1979) Reconstruction of paleotemperature of the ancient rock anomalies according to radiation defects in quartz (in Russian). Dokl Acad Nauk SSSR 248:1431–1433
Solntsev VP, Mashkovtsev RI, Scherbakova MYa (1977) Electron paramagnetic resonance of radiative centers in quartz (in Russian) J Struct Chem (USSR) 18:729–735
Stöffler D (1972) Deformation and transformation of rock-forming minerals by natural and experimental shock processes. I. Behavior of minerals under shock compression. Fortschr Mineral 49:50–113
Stöffler D (1974) Deformation and transformation of rock-forming minerals by natural and experimental shock processes. II. Physical properties of shocked minerals. Fortschr Mineral 51:256–289
Taraschan AN (1978) Luminescence of minerals (in Russian). Naukova Dumka, Kiev
Vakhidov SA, Samoilovich MI, Gasanov Z, Yarkulov U (1975) Radiative defects in quartz (in Russian). Fan, Tashkent
Valter AA, Gurov EP (1979) Shock metamorphism and shock melting — the unique natural processes connected with the formation of explosive meteorite craters. In: Fedinskii VV, Dabija AI (eds) Meteoritic structures on the planet surface (in Russian). Nauka, Moscow, pp 81–89
Valter AA, Ryabenko VA (1976) The Il'inetskaja structure — an explosive meteorite crater (in Russian). Geol J 36:42–53
Weeks RA (1963) Paramagnetic spectra of E2 centers in crystalline quartz. Phys Rev 130:570–576
Weeks RA, Nelson CM (1960) Trapped electrons in irradiated quartz and silica. II. EPR. J Am Ceram Soc 43:399–404
Wickmann HH, Klein MP, Shirley DA (1965) Paramagnetic resonance of Fe3+ in polycrystalline ferrichrome A. J Chem Phys 42:2113–2117
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Serebrennikov, A.I., Valter, A.A., Mashkovtsev, R.I. et al. The investigation of defects in shock-metamorphosed quartz. Phys Chem Minerals 8, 153–157 (1982). https://doi.org/10.1007/BF00308236
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DOI: https://doi.org/10.1007/BF00308236