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Hydrogen speciation in synthetic quartz

Physics and Chemistry of Minerals volume 11, pages 204–212 (1984)Cite this article

Abstract

The dominant hydrogen impurity in synthetic quartz is molecular H2O. H-OH groups also occur, but there is no direct evidence for the hydrolysis of Si-O-Si bonds to yield Si-OH HO-Si groups. Molecular H2O concentrations in the synthetic quartz crystals studied range from less than 10 to 3,300 ppm (H/Si), and decrease smoothly by up to an order of magnitude with distance away from the seed. OH− concentrations range from 96 to 715 ppm, and rise smoothly with distance away from the seed by up to a factor of three. The observed OH− is probably all associated with cationic impurities, as in natural quartz. Molecular H2O is the dominant initial hydrogen impurity in weak quartz. The hydrolytic weakening of quartz may be caused by the transformation H2O + Si-O-Si → 2SiOH, but this may be a transitory change with the SiOH groups recombining to form H2O, and the average SiOH concentration remaining very low. Synthetic quartz is strengthened when the H2O is accumulated into fluid inclusions and cannot react with the quartz framework.

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Author notes

  1. Roger D. Aines

    Present address: Earth Science Division, Lawrence Livermore National Laboratory, P.O. Box 808, 94550, Livermore, CA, USA

Authors and Affiliations

  1. Div. Geological and Planetary Sciences, California Institute of Technology, 91125, Pasadena, California, USA

    Roger D. Aines & George R. Rossman

  2. U.S. Geological Survey, 345 Middlefield Road, 94025, Menlo Park, California, USA

    Stephen H. Kirby

Authors
  1. Roger D. Aines
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  2. Stephen H. Kirby
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  3. George R. Rossman
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Aines, R.D., Kirby, S.H. & Rossman, G.R. Hydrogen speciation in synthetic quartz. Phys Chem Minerals 11, 204–212 (1984). https://doi.org/10.1007/BF00308135

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  • DOI: https://doi.org/10.1007/BF00308135

Keywords

  • Hydrolysis
  • Quartz
  • Mineral Resource
  • Material Processing
  • Fluid Inclusion