Abstract
Carbon and oxygen isotopic analyses of silicate and carbonate minerals indicate that isotopic compositions in metasediments of the Wallace Formation (Belt Supergroup) exposed northwest of the Idaho batholith have been affected by both prograde and retrograde fluid-rock interaction. Silicates retain isotopic fractionations that reflect equilibration at peak metamorphic temperatures. In contrast, calcite oxygen isotopic compositions range from δ18O(Calcite)=+2.3 to +18.6‰ SMOW (standard mean oceanic water) and indicate that some calcites have exchanged with low-δ18O meteorichydrothermal fluids. Values of Δ18O (Quartz-Calcite) as large as +15.5 clearly indicate that the isotopic depletion of these calcites postdates the peak of regional metamorphism. Carbon isotopic compositions of 18O-depleted calcites are not significantly shifted relative to δ13C values in undepleted calcites, suggesting that the retrograde fluid was carbon-poor. Petrographically, retrograde fluid-rock interaction is associated with the occurrence of fine-grained, highly-luminescent calcite overgrowths on less-luminescent, metamorphic calcites, slight to moderate argillic alteration, and pseudomorphing of scapolite porphyroblasts by fine-grained albite. Retrograde isotopic depletions may be related to shallow meteoric-hydrothermal fluid flow developed around the Idaho batholith after intrusion and rapid uplift of the terrane. Peak metamorphic isotopic compositions in the Wallace Formation reflect mineralogically heterogeneous protolith compositions and isotopic fractionation due to devolatilization and/or infiltration. Variability in oxygen isotopic compositions on the order of 4–6‰ within the same rock type can be attributed to the combined effects of inherited isotopic compositions and isotopic shifts resulting from prograde devolatilization. Isotopic and compositional heterogeneity on the scale of mm to m precludes generalization of isotopic gradients on a regional scale. The isotopic data presented here, and metamorphic fluid compositions determined in previous studies, are best reconciled with heterogeneous bulk compositions, dominantly channelized prograde and retrograde fluid flow, and locally low fluid-rock ratios.
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References
Baker J, Bickle MJ, Buick IS, Holland TJB, Matthews A (1989) Isotopic and petrologic evidence for the infiltration of water-rich fluids during the Miocene M2 metamorphism on Naxos, Greece. Geochim Cosmochim Acta 53:2037–2050
Bebout GE, Carlson WD (1986) Fluid evolution and transport during metamorphism: evidence from the Llano Uplift, Texas. Contrib Mineral Petrol 92:518–529
Bickle MJ, Baker J (1990) Advective-diffuse transport of isotopic fronts: an example from Naxos, Greece. Earth Planet Sci Lett 97:78–93
Bottinga Y, Iavoy M (1973) Comments on oxygen isotope geothermometry. Earth Planet Sci Lett 20:250–265
Bottinga Y, Javoy M (1975) Oxygen isotope partitioning among the minerals in igneous and metamorphic rocks. Rev Geophys Space Phys 13:401–418
Bowers TS, Helgeson HC (1983) Calculation of the thermodynamic and geochemical consequences of nonideal mixing in the system H2O−CO2−NaCl on phase relations in geologic systems: metamorphic equilibria at high temperatures and pressures. Am Mineral 68:1059–1075
Brace WF (1984) Permeability of crystalline rocks: new in situ measurements. J Geophys Res 89:4327–4330
Chamberlain CP, Ferry JM, Rumble D III (1990) The effect of net-transfer reactions on the isotopic composition of minerals. Contrib Mineral Petrol 105:322–336
Chiba H, Chacko T, Clayton RN, Goldsmith JR (1989) Oxygen isotope fractionations involving diopside, forsterite, magnetite, and calcite: applications to geothermometry. Geochim Cosmochim Acta 53:2985–2995
Clayton RN, Mayeda TK (1963) The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis. Geochim Cosmochim Acta 27:43–52
Clayton RN, Muffler LJP, White DE (1968) Oxygen isotope study of calcite and silicates of the River Ranch No. 1 well, Salton Sea Geothermal Field, California. Am J Sci 266:968–979
Clayton RN, Goldsmith JR, Mayeda TK (1989) Oxygen isotope fractionation in quartz, albite, anorthite, and calcite. Geochim Cosmochim Acta 53:725–733
Cole DR, Ohmoto H (1986) Kinetics of isotope exchange at elevated temperatures and pressures. In: Valley JW, Taylor HP, O'Neil JR (eds) Stable isotopes in high temperature geological processes. (Reviews in Mineralogy 16) Mineral Soc Am, Washington, DC, pp 41–90
Criss RE, Fleck RJ (1987) Petrogenesis, geochronology, and hydrothermal systems of the northern Idaho batholith and adjacent areas based on 18O/16O, D/H, 87Sr/86Sr, K−Ar, and 40Ar/39Ar studies. US Geol Surv Prof Pap 1436:95–137
Criss RE, Fleck RJ (1990) Oxygen isotope map of the giant metamorphic-hydrothermal system around the northern part of the Idaho batholith, USA. Appl Geochem 5:641–655
Criss RE, Taylor HP Jr (1983) An 18O/16O and D/H study of Tertiary hydrothermal systems in the southern half of the Idaho batholith. Geol Soc Am Bull 94:640–663
Criss RE, Taylor HP Jr (1986) Meteoric-hydrothermal systems. In: Valley JW, Taylor HP, O'Neil JR (eds) Stable isotopes in high temperatures geological processes. (Reviews in Mineralogy 16) Mineral Soc Am, Washington, DC, pp 373–424
Etheridge MA, Wall VJ, Vernon RH (1983) The role of the fluid phase during regional metamorphism and deformation. J Metamorphic Geol 1:205–226
Etheridge MA, Wall VJ, Cox SF, Vernon RH (1984) High fluid pressures during regional metamorphism and deformation: implications for mass transport and deformation mechanisms. J Geophys Res 89:4344–4358
Ferry JM (1986) Infiltration of aqueous fluid and high fluid: rock ratios during greenschist facies metamorphism: a reply. J Petrol 27:695–714
Fleck RJ, Criss RE (1985) Strontium and oxygen isotopic variations in Mesozoic and Tertiary plutons of central Idaho. Contrib Mineral Petrol 90:291–308
Forester RW, Taylor HP Jr (1977) 18O/16O, D/H and 13C/12C studies of the Tertiary igneous complex of Skye, Scotland. Am J Sci 277:136–177
Frey M, Hunziker JC, O'Neil JR, Schwander HW (1976) Equilibrium-disequilibrium relations in the Monte Rosa Granite, W Alps: petrological, Rb−Sr and stable isotope data. Contrib Mineral Petrol 55:147–179
Friedman I, O'Neil JR (1977) Compilation of stable isotope fractionation factors of geochemical interest. US Geol Surv Prof Pap 440 KK
Ganor J, Matthews A, Paldor N (1989) Constraints on effective diffusivity during oxygen isotope exchange at a marble-schist contact, Sifnos (Cyclades), Greece. Earth Planet Sci Lett 94:208–216
Garlick GD, Epstein S (1967) Oxygen isotope ratios in coexisting minerals of regionally metamorphosed rocks. Geochim Cosmochim Acta 31:181–214
Graham CM, Grieg KM, Sheppard SMF, Turi B (1983) Genesis and mobility of the H2O−CO2 fluid phase during regional greenschist and epidote-amphibolite facies metamorphism: a petrological and stable isotope study in the Scottish Dalradian. J Geol Soc London 140:577–599
Grover TW, Rice JM, Ruendal A, Carey JW, Lang HM (1987) Polymetamorphic history of the St. Joe-Clearwater region of northern Idaho (abstract). Geol Soc Am Abstr Program 19:384
Hietanen AH (1962) Metasomatic metamorphism in western Clearwater County Idaho. US Geol Surv Prof Pap 344-A
Hietanen AH (1963) Metamorphism of the Belt Series in the Elk River-Clarkia area, Idaho. US Geol Surv Prof Pap 344-C
Hietanen AH (1967) Scapolite in the Belt Series in the St. Joe-Clearwater Region, Idaho. Geol Soc Am Spec Pap 86
Hietanen AH (1968) Belt series in the region around Snow Peak and Mallard Peak, Idaho. US Geol Surv Prof Pap 344-E
Hietanen AH (1984) Geology along the northwest border zone of the Idaho batholith, northwest Idaho. US Geol Surv Bull 1608
Hoernes S, Friedrichsen H (1978) Oxygen and hydrogen isotope study of the polymetamorphic area of the Northern Otzal-Stubai Alps. Contrib Mineral Petrol 67:305–315
Holness MB, Graham CM (1991) Equilibrium dihedral angles in the system H2O−CO2−NaCl-calcite and implications for fluid flow during metamorphism. Contrib Mineral Petrol (in press)
King EJ, Rice JM (1984) Scapolite-plagioclase equilibria in regionally metamorphosed calc-schists, Bluff Creek, Idaho (abstract). Geol Soc Am Abstr Program 16:559
Knight RV (1986) Metamorphism of Belt Supergroup calc-silicate rocks northwest of the Idaho batholith. Unpubl MS Thesis, University of Utah
Knight RV, Bowman JR (1985) Metamorphism of Belt Supergroup calc-silicate rocks in the northwest border zone of the Idaho batholith. Trans Am Geophys Union 66:1126
Lang HM, Rice JM (1985a) Metamorphism of pelitic rocks in the Snow Peak area, northern Idaho: sequence of events and regional implications. Geol Soc Am Bull 96:731–736
Lang HM, Rice JM (1985b) Geothermometry, geobarometry and T-X(Fe−Mg) relations in metapelites. Snow Peak, northern Idaho. J Petrol 26:889–924
Larson PB, Taylor HP Jr (1986) 18O/16O relationships in hydrothermally altered rocks from the Lake City caldera, San Juan Mtns., Colorado. J Volcanol Geothermal Res 30:47–82
Magaritz M, Taylor HP Jr (1976) Isotopic evidence for meteoric-hydrothermal alteration of plutonic igneous rocks in the Yakutat Bay and Skagway areas, Alaska. Earth Planet Sci Lett 30:179–190
Marshall DJ (1988) Cathodoluminescence of geological materials. Unwin Hyman, Boston
Matthews A, Schliestedt M (1984) Evolution of the blueschist and greenschist facies rocks of Sifnos, Greece. Contrib Mineral Petrol 88:150–163
McCrea JM (1950) The isotopic chemistry of carbonates and a paleotemperature scale. J Chem Phys 18:849–857
Mora Cl (1988) Fluid-rock interaction in scapolite-bearing Belt Group metasediments northwest of the Idaho batholith. Unpubl PhD Thesis, University Wisconsin-Madison
Mora Cl, Valley JW (1988) Channelized meteoric-hydrothermal alteration of the Boehls Butte and Bitterroot anorthosites, northern ID and MT. Trans Am Geophys Union 69:1489
Mora Cl, Valley JW (1989) Halogen-rich scapolite and biotite: implications for metamorphic fluid-rock interaction. Am Mineral 74:721–737
Morrison J, Valley JW (1988) Post-granulite facies fluid infiltration in the Adirondack Mountains. Geology 16:513–516
Munoz JL, Swenson A (1981) Chloride-hydroxyl exchange in biotite and estimation of relative HCl/HF activities in hydrothermal fluids. Econ Geol 76:2212–2221
Oliver NHS, Valenta RK, Wall VJ (1990) The effect of heterogeneous stress and strain on metamorphic fluid flow, Mary Kathleen, Australia, and a model for large-scale fluid circulation. J Metamorphic Geol 8:311–331
O'Neil JR, Ghent ED (1975) Stable isotope study of coexisting metamorphic minerals from the Esplanade Range, British Columbia. Geol Soc Am Bull 97:1708–1712
Rice JM, Ferry JM (1982) Buffering, infiltration and the control of intensive variables during metamorphism. In: JM Ferry (ed) Characterization of metamorphism through mineral equilibria. (Reviews in Mineralogy 10) Mineral Soc Am, Washington, DC, pp 263–326
Ruendal A, Rice JM (1987) Garnet zoning and P-T paths of metamorphism, Headquarters region, northern Idaho (abstract). Geol Soc Am Abstr Program 49:446
Rumble D III (1982) Stable isotopic fractionation during metamorphic devolatilization reactions. In: Ferry JM (ed) Characterization of metamorphism through mineral equilibria. (Reviews in Mineralogy 10) Mineral Soc Am, Washington, DC, pp 327–352
Rumble D III, Ferry JM, Hoering TC (1986) Oxygen isotope geochemistry of hydrothermally-altered synmetamorphic granitic rocks from south-central Maine, USA. Contrib Mineral Petrol 93:420–428
Rye RO, Schuiling RD, Rye DM, Jansen JBH (1976) Carbon, hydrogen, and oxygen isotope studies of the regional metamorphic complex at Naxos, Greece. Geochim Cosmochim Acta 40:1031–1049
Shieh YN, Schwarcz HP (1974) Oxygen isotope studies of granite and migmatite, Grenville province of Ontario, Canada. Geochim Cosmochim Acta 38:21–45
Sommer SE (1972) Cathodoluminescence of carbonates I: characterization of cathodoluminescence from carbonate solid solution. Chem Geol 9:257–273
Taylor HP Jr (1969) Oxygen isotopic studies of anorthosites, with particular reference to the origin of bodies in the Adirondack Mountains, New York. In: Isachsen YW (ed) Origin of anorthosite and related rocks. NY State Mus Sci Serv Mem 18, pp 111–134
Taylor HP Jr (1971) Oxygen isotope evidence for large-scale interaction between meteoric ground waters and Tertiary granodiorite intrusions, western Cascade Range, Oregon. J Geophys Res 76:7855–7874
Taylor HP Jr, Forester RW (1979) An oxygen and hydrogen isotope study of the Skaergaard intrusion and its country rocks: a description of a 55-M.Y. old fossil hydrothermal system. J Petrol 20:355–419
Taylor HP Jr, Albee AL, Epstein S (1963) 18O/16O ratios of coexisting minerals in three assemblages of kyanite-zone pelitic schist. J Geol 71:513–522
Tomten DC, Bowman JR (1984) Geothermometry and geobarometry of metamorphosed Belt Series, northwest of the Idaho batholith, Idaho. Trans Am Geophys Union 65:1148
Tracy RJ, Rye DM, Hewitt DA, Schiffries CM (1983) Petrologic and stable isotopic studies of fluid-rock interactions, south-central Connecticut I: the role of infiltration in producing reaction assemblages in impure marbles. Am J Sci 283A:589–616
Trommsdorff V, Skippen GS (1986) Vapour loss (“boiling”) as a mechanism for fluid evolution in metamorphic rocks. Contrib Mineral Petrol 94:317–322
Truesdell AH (1974) Oxygen isotope activities and concentrations in aqueous salt solutions at elevated temperatures — consequences for isotope geochemistry. Earth Planet Sci Lett 23:387–396
Valley JW (1986) Stable isotope geochemistry of metamorphic rocks. In: Valley JW, Taylor HP, O'Neil JR (eds) Stable isotopes in high temperature geological processes. (Reviews in Mineral 16) Mineral Soc Am, Washington, DC, pp 445–489
Valley JW, O'Neil JR (1984) Fluid heterogeneity during granulite facies metamorphism in the Adirondacks: stable isotopic evidence. Contrib Mineral Petrol 85:158–173
Valley JW, Bohlen SR, Essene EJ, Lamb W (1990) Metamorphism in the Adirondacks II: the role of fluids. J Petrol 31:555–596
Veizer J, Hoefs J (1976) The nature of 18O/16O and 13C/12C secular trends in sedimentary carbonate rocks. Geochim Cosmochim Acta 40:1387–1395
Volfinger M, Robert JL, Vielzeuf D, Neiva MR (1985) Structural control of the chlorine content of OH-bearing silicates (micas and amphiboles). Geochim Cosmochim Acta 49:37–48
Watson EB, Brenan JM (1987) Fluids in the lithosphere, 1: experimentally-determined wetting characteristics of CO2−H2O fluids and their implications for fluid transport, host-rock physical properties, and fluid inclusion formation. Earth Planet Sci Lett 85:497–515
Wickham SM, Taylor HP Jr (1985) Stable isotope evidence for large-scale seawater infiltration in a regional metamorphic terrane: the Trois Seigneurs Massif, Pyrenees, France. Contrib Mineral Petrol 91:122–137
Wood BJ, Graham CM (1986) Infiltration of aqueous fluid and high fluid: rock ratios during greenschist facies metamorphism: a discussion. J Petrol 27:751–761
Wood BJ, Walther JV (1986) Flund flow during metamorphism and its implications for fluid-rock ratios. In: Walther JV, Wood BJ (eds) Fluid-rock interactions during metamorphism. Springer, Berlin Heidelberg New York, pp 89–108
Yardley BWD, Bottrell SH (1988) Immiscible fluids in metamorphism: implications of two-phase flow for reaction history. Geology 16:199–202
Yardley BWD, Lloyd GE (1989) An application of cathodoluminescence microscopy to the study of textures and reactions in high-grade marbles from Connemara, Ireland. Geol Mag 126:333–337
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Mora, C.I., Valley, J.W. Prograde and retrograde fluid-rock interaction in calc-silicates northwest of the Idaho batholith: stable isotopic evidence. Contr. Mineral. and Petrol. 108, 162–174 (1991). https://doi.org/10.1007/BF00307335
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DOI: https://doi.org/10.1007/BF00307335