Summary
Graft copolymers of acryloylchloride (AC) with polyethylene (PE) and polyethyl eneterephtalate (PET) have been synthesized by grafting of AC from the vapor phase under mutual γ-irradiation. It has been shown that both the amount of grafted reactive chains and their structure was determined by the polymer: monomer ratio and the total irradiation dose. The high grafting degree of reactive groups and their ability to interact with free amino groups of biological molecules both in organic media and in water solutions make these functionalized polymers suitable as reactive carriers for covalent immobilization of various amino groups containing compounds.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Labonesse, J. Gervais, M. (1967), Eur. J. Biochem. 2:215
Hoffman, A.S. (1984) Adv. Polym. Sci., 57:141
Arshady, R. (1992), J. Macromol. Sci., C32:101
Ito, Y., Lin, L.S., Yamanishi, J. (1992), J. Biomed. Mater. Res., 26:1065
Johnson, P.E., Dettre, R.H. (1992), Adv. Chem., Series No., 12:43
Burdygina, I.F., Chupov, V.V., Valuev, L.I., Alexandrova, L.B., Golubev, V.B., Platé, N.A. (1982), Polymer Sci. USSR, A-24:372
Naka, Y., Jamamoto, Y. (1992), J. Appl. Pol. Sci., 45:1287
Platé, N.A., Valuev, L.I., Chupov, V.V. (1984), Pure Appl. Chem., 56:1351.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chupov, V.V., van der Does, L., Platé, N.A. et al. Polymeric carriers for covalent immobilization of amino groups containing compounds. Polymer Bulletin 32, 229–233 (1994). https://doi.org/10.1007/BF00306393
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00306393