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Miscible blends of poly(n-vinyl-2-pyrrolidone) with poly(3-chloropropyl methacrylate), poly(2-bromoethyl methacrylate) and poly(2-iodoethyl methacrylate)

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Summary

Poly(N-vinyl-2-pyrrolidone) is miscible with poly(3-chloropropyl methacrylate), poly(2-bromoethyl methacrylate) and poly(2-iodoethyl methacrylate) as shown by the optical clarity and the glass transition behaviour of the blends. The miscible blends degrade before phase separation could be induced by heating. The three Tg-composition curves can be fitted by the Gordon-Taylor equation. The implication of the Gordon-Taylor k parameters of the blends is discussed.

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References

  1. Moskala EJJ, Varnell D F, Coleman M M (1985) Polymer 26, 228

    Google Scholar 

  2. Eguaizabal J I, Iruin J J, Cortazar M, Guzman G M (1984) Makromol Chem 185, 1761

    Google Scholar 

  3. Peng Z H, Nguyen Q T, Neel J (1989) Makromol Chem 190, 437

    Google Scholar 

  4. Peng Z H, Nguyen Q T, Neel J (1989) Makromol Chem, 191, 185

    Google Scholar 

  5. Thyagarajan G, Janarthanan V (1989) Polymer 30, 1797

    Google Scholar 

  6. Nishio T, Haratani T, Takahashi T (1990) J Polym Sci Polym Phys Edn 28, 355

    Google Scholar 

  7. Goh S H, Siow K S (1990) Polym Bull 23, 205

    Google Scholar 

  8. Goh S H, Lee S Y (1990) Makromol Chem 191, 3081

    Google Scholar 

  9. Lee S Y, Low M Y, Goh S H (1991) Eur Polym J 27, 1379

    Google Scholar 

  10. Guo Q (1990) Makromol Chem Rapid Commun 11, 279

    Google Scholar 

  11. Neo M K, Goh S H (1991) Polym Commun 32, 200

    Google Scholar 

  12. Low S M, Lee S Y, Goh S H (1993) Eur Polym J (in press)

  13. Neo M K, Lee S Y, Goh S H (1991) Macromolecules 24, 2564

    Google Scholar 

  14. Low S M, Lee S Y, Goh S H (1993) Macromolecules 26, 2631

    Google Scholar 

  15. Low S M, Lee S Y, Goh S H (1993) Eur Polym J 29, 909

    Google Scholar 

  16. Tan Y T, Challa G (1976) Polymer 17, 739

    Google Scholar 

  17. Turner D T, Schwartz A (1985) Polymer 26, 757

    Google Scholar 

  18. Goh S H, Lee S Y, Siow K S, Neo M K (1990) Polymer 31, 1065

    Google Scholar 

  19. Brandrup J, Immergut E H (Eds) (1989) Polymer Handbook, 3rd Ed, Wiley-Interscience, New York

    Google Scholar 

  20. Van Krevelen D W (1990) Properties of Polymer, Elsevier Science Publishers, Amsterdam

    Google Scholar 

  21. Prud'homme, R E (1982) Polym Eng Sci 22, 90

    Google Scholar 

  22. Belorgey G, Prud'homme R E (1982) J Polym Sci Polym Phys Ed 20, 191

    Google Scholar 

  23. Neo M K, Lee S Y, Goh S H (1991) J Appl Polym Sci 43, 1031

    Google Scholar 

  24. Low S M, Goh S H, Lee S Y paper in preparation

  25. Dewar M J S, Zoebisch, E G, Healy E F, Stewart J J P (1986) QCPE Bull 6, 24

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, National University of Singapore, 0511, Singapore, Republic of Singapore

    S. M. Low, S. H. Goh, S. Y. Lee & M. K. Neo

Authors
  1. S. M. Low
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  2. S. H. Goh
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  3. S. Y. Lee
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  4. M. K. Neo
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Low, S.M., Goh, S.H., Lee, S.Y. et al. Miscible blends of poly(n-vinyl-2-pyrrolidone) with poly(3-chloropropyl methacrylate), poly(2-bromoethyl methacrylate) and poly(2-iodoethyl methacrylate). Polymer Bulletin 32, 187–192 (1994). https://doi.org/10.1007/BF00306387

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  • DOI: https://doi.org/10.1007/BF00306387

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