Abstract
Volume-weighted pH values in central New Mexico have averaged 3.8 to 5.1 during the period 1979–1985. Samples collected at a high altitude site (3200m) have lower pH values than found for low altitude samples (1400m). Both dry deposition and event-averaged pH values have been higher than the volume-weighted averages due to neutralization by terrestrial material. During the period 1980–1984, changes in pH values and wet sulfate loading have correlated to S02 emissions from regional non-ferrous smelters. Sulfur isotope analyses of sulfate extracted from regional rain samples yielded a δ34SCD(%) of + 3.91 ± 1.1, indicating very little regional differentiation which, in turn, suggests that the regional atmospheric sulfate scavenged by precipitation is well-mixed and relatively homogeneous.
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References
Ashbaugh, L.L., Myrup, L.O., and Flocchini, R.G.: 1984, ‘A Principal Component Analysis of Sulfur Concentrations in the Western United States’, Atmos. Environ., 18, 783–791.
Buchholz, A.E., Verplough, C.I., and Smith J.L.: 1982, ‘A Method for the Simultaneous Measurement of Less Than a Part-Per-Million of Chloride, Nitrate, and Sulfate in Aqueous Samples by Nonsuppressed Ion Chromatography’, J. Chromatogr. Sci., 20, 449–501.
Esstoc, C.J.: personal communication.
Grant, M.C. and Lewis, Jr., W.M.: 1982, ‘Chemical Loading Rates from Precipitation in the Colorado Rockies’, Tellus, 34, 74.
Hoefs, J.: 1980, Stable Isotope Geochemistry, 2nd Ed., Springer-Verlag, NY, p. 44.
Huebert, B.J., Norton, R.B., Bollinger, M.J., Parrish, D.D., Hahn C., Bush, Y.A., Murphy, P.C., Fehsenfeld, F.C., and Albritton, D.L.: 1982, ‘Gas Phase and Precipitation Acidities in the Colorado Mountains’, In Proc. Int. Sympo.on Hydrometeorology, American Water Resource Association, 17.
Lewis, Jr., W.M. Grant, M.C., and Saunders, III, J.F.: 1984, ‘Chemical Patterns of Bulk Atmospheric Deposition in the State of Colorado’, Water Resource Res., 20, 1691.
Lewis, Jr., W. M. and Grant M.C.:1981, ‘Acid Precipitation in the Western United States’, Science, 207, 176.
New Mexico Air Quality Bureau: 1985, Department of Health and Environment, Santa Fe, New Mexico.
Nielson, H.: 1974, ‘Isotope Composition of the Major Contributors to Atmospheric Sulfur’, Tellus, 26, 213.
Niemann, B.L.: 1985, ‘Critical Analysis of Regional Acid Deposition Source-Receptor Relationships for Smelters in the Intermountain West’. Presented at the International Conference on Acidic Precipitation, Muskoka, Ontario.
Oppenheimer, M., Epstein, C.B., and Yuhnke, R.E.: 1985, ‘Acid Deposition, Smelter Emissions, and the Linearity Issue in the Western United States’, Science, 229, 859–862.
Popp, C.J., Jensen, C.M., Brandvold, D.K. and Brandvold, L.A.: 1982, ‘Precipitation Analysis in Central New Mexico’, In Energy and the Environment, II, Ann Arbor Science Press, Ann Arbor, Michigan.
Popp, C.J., Brandvold, D.C., Ohline, R.W., and Brandvold, L.A.: 1984, ‘Nature of Precipitation and Atmospheric Particulates in Central and Northern New Mexico’, In Deposition, Both Wet and Dry, Ann Arbor Science Press, Ann Arbor, Michigan.
USEPA: 1979, ‘Methods for the Analyses of Water and Wastes’, EPA-600014-79-020, U.S. EPA, Cincinnati, OH.
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Popp, C.J., Brandvold, D.K., Long, A. et al. Acidic precipitation in Western North America: Trends, sources, and altitude effects in New Mexico 1979–1985. Water Air Soil Pollut 30, 125–133 (1986). https://doi.org/10.1007/BF00305181
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DOI: https://doi.org/10.1007/BF00305181