Skip to main content
SpringerLink
Log in

Diacetylene containing polymers

I. Poly(m,m′-butadiynylene dibenzylterephthalate)

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

A polyester containing diacetylenic units in main chain was prepared by the polycondensation of m, m′-butadiynylene dibenzyl alcohol with terephthaloyl chloride. The polymer was crystalline, and bearly soluble in hot dimethylformamide or dimethylsulfoxide, but insoluble in most organic solvents. It melts at about 200°C. Irradiation of UV light at 75°C gave a reddish brown resin. Heating at temperatures above its melting point gave a shinning black hard solid.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. WEGNER,G., Z. Natuforsch, 24B, 824(1969)

    Google Scholar 

  2. SMITH,P.W., Bell Syst. Tech. J., 61 1975(1982)

    Google Scholar 

  3. CHAMELA,D.S., and ZYSS,J., Editors, “Nonlinear Optical Properties of Organic Molecules and Crystals”, vol. 2, Chapt. III-3, pp85–119, Academic Press (London) Itd., 1987.

    Google Scholar 

  4. TIEKE,B., WEGNER,G. NAEGALE,D., and RINGSDORF,H., Angew. Chem. Int. Ed., 12, 764(1976).

    Google Scholar 

  5. BURILLO,G., CARREON,P., OGAWA,T., SOTELO,M., up-And NAVARRO,R.E., Polym. Commun., 32, No. 8, 248(1991)

    Google Scholar 

  6. BARDAMOVA,M.I., SHISHMAKOVA,T.G., up-And KOTLYAREVSKII,I.D., Visokomol. Soedin., Ser. B, 9(11), 807(1967); Chem. Abst. 68, 30218 y (1968); llvz. Akad. Nauk. SSSR, Ser. Khim. (3), 685–62(1967).

    Google Scholar 

  7. HAY,A.S., BOLON,D.A., LEIMER,K.R., and CLARK,R.F., J. Polym. Sci., Poly. Lett. Ed., 8, 97(1970).

    Google Scholar 

  8. WEGNER,G., Die Makromol. Chem., 134, 219(1980).

    Google Scholar 

  9. DAY,D., and LANDO,J.B., J.Polym. Sci., Polym. Lett. Ed., 19, 277(1981).

    Google Scholar 

  10. FUJIWARA,H., and KIHARA,K., Jpn. Kokai Tokkyo Koho, JP. 01,311,113 (1989). Chem. Abst. 112, 218178s(1990).

Download references

Author information

Authors and Affiliations

  1. Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, México, Mexico

    Josefina Pérez & Guillermina Burillo

  2. Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, México, Mexico

    Martha Roa, Carmen Vázquez & Takeshi Ogawa

Authors
  1. Josefina Pérez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Guillermina Burillo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Martha Roa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Carmen Vázquez
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Takeshi Ogawa
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pérez, J., Burillo, G., Roa, M. et al. Diacetylene containing polymers. Polymer Bulletin 27, 527–534 (1992). https://doi.org/10.1007/BF00300600

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00300600

Keywords

Search

Navigation