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Synthesis and investigation of α,ω-methacryloyl terminated epoxide-amine macromonomers

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Summary

α,ω-methacryloyl-poly (epoxide-amine)-macromonomers were synthesized by reaction of bisphenol-A diglycidylether DGEBA and methacrylic acid followed by addition polymerization of unreacted expoxide groups with primary monoamines or disecondary diamines, respectively. The resultant macromonomers having Mn (vpo)-values between 530 and 2000 g/mol were analysed by IR-, 1H-NMR- and 13C-NMR-spectroscopy. HPLC and GPC analysis were used to determine the distribution of oligomers. The macromonomers are glassy or viscous liquids with Tg between 0 and 50 °C depending on the nature of the amine and polymerization degree.

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References

  1. P.F. Rempp, E. Franta, Adv.Polym.Sci. 58, 1 (1984)

    Google Scholar 

  2. V. Percec, C. Pugh, O. Nuyken, D. S. Pask, “Macromonomers, Oligomers and telechelic Polymers” in “Comprehensive Polymer Science”, ed. by G. Allen, J. C. Bevington, Pergamon Press Ltd., Oxford 1989, Vol.6, 281

    Google Scholar 

  3. G. Greber, E. Reese, Makromol. Chem. 55, 96 (1962)

    Google Scholar 

  4. G. O. Shulz, R. Milkovic, J. Appl. Polym. Sci. 27, 4773 (1982)

    Google Scholar 

  5. P. Masson, E. Franta, P. Rempp, Makromol. Chem., Rapid Commun. 3 499 (1982)

    Google Scholar 

  6. P. Masson, G. Beinert, E. Franta, P. Rempp, Polym. Bull. 7, 17 (1982)

    Google Scholar 

  7. P. Siegwalt, Angew. Makromol. Chem. 94, 1101 (1981)

    Google Scholar 

  8. J. Sierra-Vargas, J. G. Zilliox, P. Rempp, E. Franta, Polym. Bull. 3, 83 (1980)

    Google Scholar 

  9. P. R. Rao, P. Masson, P. Lutz, G. Beinert, P. Rempp, Polym. Bull. 11, 115 (1985)

    Google Scholar 

  10. F. Severini, M. Pegoraro, L. Saija, Angew.Makromol.Chem. 133, 111 (1985)

    Google Scholar 

  11. J. Klee, H.-H. Hörhold, H. Schütz, Acta Polym. 42, 17 (1991)

    Google Scholar 

  12. J. Klee, H.-H. Hörhold, W. Tänzer, M. Fedtke, Acta Polym. 37, 272 (1986)

    Google Scholar 

  13. J. Klee, H.-H. Hörhold, W. Tänzer, H. Fedtke, Angew.Makromol.Chem. 147, 71 (1987)

    Google Scholar 

  14. H. E. Grethlein, Int. Eng. Chem., Fundamentals 8, 206 (1969)

    Google Scholar 

  15. L. C. Case, J.Polym.Sci., 29, 455 (1958)

    Google Scholar 

Download references

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Authors and Affiliations

  1. Chemical Faculty, Friedrich-Schiller-University, O-6900, Jena, Federal Republic of Germany

    Joachim Klee, Frank Claußen & Hans-Heinrich Hörhold

  2. Direktion Forschung, Leuna-Werke AG, O-4200, Merseburg, Federal Republic of Germany

    Joachim Raddatz

Authors
  1. Joachim Klee
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  2. Frank Claußen
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  3. Hans-Heinrich Hörhold
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  4. Joachim Raddatz
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Klee, J., Claußen, F., Hörhold, HH. et al. Synthesis and investigation of α,ω-methacryloyl terminated epoxide-amine macromonomers. Polymer Bulletin 27, 511–517 (1992). https://doi.org/10.1007/BF00300598

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  • DOI: https://doi.org/10.1007/BF00300598

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