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Synthesis of a perfluorinated azo initiator

Application to the determination of the recombination/disproportionation rate during the polymerization of styrene

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Summary

A method to determine the recombination/disproportionation rate during the polymerization of styrene is described. In this method, a perfluorinated azo initiator used to prepare a perfluorinated polystyrene was first synthesized. Then, the recombination/disproportionation rate was calculated by comparing the number-average molecular weight \((\overline {{\text{DP}}} _{\text{n}} )\)and the fluorine content in weight of this resulting polystyrene.

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Authors and Affiliations

  1. URA D 11930 CNRS, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue Ecole Normale, F-34053, Montpellier Cédex 01, France

    Jean-Marie Bessière, Bernard Boutevin & Olivier Loubet

Authors
  1. Jean-Marie Bessière
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  2. Bernard Boutevin
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  3. Olivier Loubet
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Bessière, JM., Boutevin, B. & Loubet, O. Synthesis of a perfluorinated azo initiator. Polymer Bulletin 31, 673–677 (1993). https://doi.org/10.1007/BF00300126

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  • DOI: https://doi.org/10.1007/BF00300126

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