Summary
A pentacomponent acrylate copolymer containing hydroxyl and carboxyl groups was grafted with a semi-blocked polyurethane prepolymer and then deblocked to get polymer network with carboxyl groups. The network polymer can swell at pH range 6–13 and swell has reversible characteristic up to pH 11.Moreover, swelling kinetics is belong to a non-Fickian type.
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References
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Yu, M.X., Zhang, W.H. pH-sensitivity of swelling of polyurethane crosslinked polyacrylate network. Polymer Bulletin 30, 719–724 (1993). https://doi.org/10.1007/BF00300042
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DOI: https://doi.org/10.1007/BF00300042