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Miscibility of some phenoxy/polymethacrylate blends

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Summary

It has been reported that phenoxy is miscible with poly(methyl methacrylate), poly(tetrahydrofurfuryl methacrylate) and poly(tetrahydropyranyl-2-methyl methacrylate). However, we have found that phenoxy is immiscible with poly(ethyl methacrylate), poly(n-propyl methacrylate), poly(n-butyl methacrylate), poly(methylthiomethyl methacrylate), poly(methoxymethyl methacrylate) and poly(methoxycarbonylmethyl methacrylate). The miscibility behavior of various phenoxy/polymethacrylate blends cannot be satisfactorily explained by a non-hydrogen-bonded solubility parameter approach.

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Goh, S.H., Lee, S.Y., Siow, K.S. et al. Miscibility of some phenoxy/polymethacrylate blends. Polymer Bulletin 30, 691–696 (1993). https://doi.org/10.1007/BF00300038

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  • DOI: https://doi.org/10.1007/BF00300038

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