Summary
Unimodal, bimodal, and trimodal networks were prepared by end linking functionally-terminated chains of poly(dimethylsiloxane). The resulting materials were characterized using a “thermoporometric” technique in which freezing points or melting points are determined for solvent absorbed into the network stuctures. The extent to which the normal melting point is suppressed depends on how much the solvent is constrained within the network pores. Several well-defined melting points were observed for some of the multimodal networks, which is consistent with their unusual distributions of network chain lengths.
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References
Llorente, M. A., Andrady, A. L., and Mark, J. E., J. Polym. Sci., Polym. Phys. Ed., 19, 621 (1981).
Curro, J. G. and Mark, J. E., J. Chem. Phys., 80, 4521 (1984).
Sun, C.-C. and Mark, J. E., J. Polym. Sci., Polym. Phys. Ed., 25,2073 (1987).
Galiatsatos, V. and Mark, J. E., Macromolecules, 20, 2631 (1987).
Mark, J. E. and Erman, B., “Rubberlike Elasticity. A Molecular Primer”, Wiley-Interscience, New York, 1988.
Erman, B. and Mark, J. E., J. Chem. Phys., 89, 3314 (1988).0
Galiatsatos, V. and Mark, J. E. in “Advances in Silicon-Based Polymer Science”, ed. by J. M. Zeigler and F. W. G. Fearon, American Chemical Society, Washington, 1990.
Silva, L. K., Mark, J. E., and Boerio, F. J., Makromol. Chem., 192, 499 (1991).
Wang, S., Ph. D. Thesis in Chemistry, The University of Cincinnati, 1991.
Xu, P., Ph. D. Thesis in Chemistry, The University of Cincinnati, 1991.
Xu, P., and Mark, J. E., J. Polym. Sci., Polym. Phys. Ed., 29, 355 (1991).
Andrady, A. L., Llorente, M. A., and Mark, J. E., Polym. Bulletin, 26, 357 (1991).
Xu, P. and Mark, J. E., Polymer, 33, 1843 (1992).
Wang, S. and Mark, J. E., J. Polym. Sci., Polym. Phys. Ed., 30, 801 (1992).
Clarson, S. C., Mark, J. E., Sun, C.-C., and Dodgson, K., Eur. Polym. J., 28, 823 (1992).
Madkour, T., Ph.D. Thesis in Chemistry, The University of Cincinnati, 1993.
Mark, J. E., submitted to J. Inorg. Organomet. Polym.
Flory, P. J., “Principles of Polymer Chemistry”, Cornell University Press, Ithaca, New York, 1953.
Treloar, L. R. G., “The Physics of Rubber Elasticity”, 3rd Ed., Clarendon Press, Oxford, 1975.
Goldstein, A. N., Esher, C. M., and Alivisatos, A. P., Science, 256, 1425 (1992), and pertinent references cited therein.
Jackson, C. L. and McKenna, G. B., J. Chem. Phys. 93, 9002 (1990).
Jackson, C. L. and McKenna, G. B., J. Non-Cryst. Solids, 131–133, 221 (1991).
Phalippou, J., Ayral, A., Woignier, T., and Quinson, J. F., Europhys. Lett., 14, 249 (1991).
Ehrburger-Dolle, F., Misono, S., and Lahaye, J., J. Colloid Interface Sci. 135, 468 (1990).
Ma, W.-J., Banavar, J. R., and Koplik, J., J. Chem. Phys., 97, 485 (1992).
Kuhn, W., Peterli, E., and Majer H., J. Polym. Sci., 16 539 (1955).
Kuhn, W. and Majer H., Angew. Chem., 68, 345 (1956).
Kuhn, W., Peterli, E., and Majer H., Rubber Chem. Technol. 33, 245 (1960).
Boonstra, B. B., Heckman, F. A., Taylor, G. L., J. Appl. Polym. Sci., 12, 223 (1968).
Quinson, J. F., Actual Chim., 8, 21 (1979).
Oikawa, H. and Murakami, K., Polymer, 25, 225 (1984).
Murakami, K., Polymer, 27, 1563 (1986).
Murase, N., Gonda, K., and Watanabe, T., J. Phys. Chem., 90, 5420 (1986).
Mayen, M., Eur. Polym. J., 22, 987 (1986).
Honiball, D., Huson, M. G., and McGill, W. J., J. Polym. Sci., Polym. Phys. Ed., 26, 2413 (1988).
Pouchelon, A., Soria, M., and Moll, L., Makromol. Chem. Macromol. Symp., 40, 147 (1990).
Arndt, K. F. and Zander, P., Colloid Polym. Sci., 268, 806 (1990), and pertinent references cited therein.
Jackson, C. L. and McKenna, G. B., Rubber Chem. Technol., 64, 760 (1991).
Grobler, J. H. A. and McGill, W. J., J. Polym. Sci., Polym. Phys. Ed., 31, 575 (1993).
Mark, J. E. and Sullivan, J. L., J. Chem. Phys., 66, 1006 (1977).
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Madkour, T., Mark, J.E. Some evidence on pore sizes in poly(dimethylsiloxane) elastomers having unimodal, bimodal, or trimodal distributions of network chain lengths. Polymer Bulletin 31, 615–621 (1993). https://doi.org/10.1007/BF00297900
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DOI: https://doi.org/10.1007/BF00297900