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Reactions of organoboron polymers prepared by hydroboration polymerization

III. Synthesis of poly(alcohol)s by the reaction with α,α-dichloromethyl methyl ether

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Summary

Hydroboration polymerization of diolefin gives an organoboron polymer, which can be regarded as a polymer homologue of trialkylborane. The organoboron polymers obtained were reacted with α,α-dichloromethyl methyl ether (DCME) followed by the oxidative treatment to produce the corresponding poly(alcohol)s in high yields.

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Authors and Affiliations

  1. Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo-ku, 606, Kyoto, Japan

    Yoshiki Chujo, Ikuyoshi Tomita & Takeo Saegusa

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  1. Yoshiki Chujo
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  2. Ikuyoshi Tomita
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  3. Takeo Saegusa
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Part II: Polym. Bull. 25,1 (1991)

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Chujo, Y., Tomita, I. & Saegusa, T. Reactions of organoboron polymers prepared by hydroboration polymerization. Polymer Bulletin 26, 165–168 (1991). https://doi.org/10.1007/BF00297521

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  • DOI: https://doi.org/10.1007/BF00297521

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