Summary
Pyromellitic dianhydride and dipyridyl/dipyridylamine have been polycondensed in presence of anhydrous ZnCl2 under selective conditions. Fe(III), Cr(III), Co(II), Ni(II) and Cu(II) complexes of the polycondensates have been prepared. Tentative structures for PMDA-DP (DPA)-M complexes have been proposed on the basis of elemental IR and electronic spectral analyses.
Similar content being viewed by others
References
J. Sheats, C. Carraher, M. Zeldin, B. Currell and C. Pittman, Jr. Abstracts ACS Symposium in Inorganic and Metal Containing Polymeric Materials Miami, USA, Sept. 1989, page 91–93.
M. Biswas and S. Moitra, J. Appl. Polymer Sci., 38, 1243 (1989)
M. Biswas, S Moitra and T Uryu Polymer Communications, 30, 225 (1989)
M. Biswas and S. Moitra, J. Polymer Materials, 7 89 (1990)
A S Brar, R G Mendiratta, M. Biswas and S. Moitra, Polymer Communication, 31, 237 (1990)
R.D. Archer, C.J. Hardiman, J.S. Kim, E.R. Grandbois and M. Goldstein in Metal Containing Polymer System. Ed. J.E. Sheats, C.C. Carraher Jr. and C.U. Pittman Jr. Plenum Press, New York, 1983, p.353
C.E. Carraher Jr. and C.U. Pittman, Jr. in Metal Containing Polymer System. Ed. J.E. Sheats, C.C. Carraher Jr. and C.U. Pittman Jr. Plenum Press, New York, 1983, p. 2
Dyer, J, Application of Absorption Spectroscopy of Organic Compounds, Prentice Hall, India, 1984, Ch.3.
M.C. Feller and R. Robson, Aus. J. Chem. 21, 2991 (1968)
R. Kratz, G.D. Hendricker, Polymer, 27, 1641 (1986)
R.R. Osborne and W.R. McWhinne, J. Chem. Soc.(A), 2075 (1967)
I.J. Bukker, M.C. Feller and R. Robson, J. Inorg. Nucl. Chem., 33, 743 (1971).
A.P.B. Lever, Inorganic Electronic Spectroscopy, 2nd Ed., Elsevier, New York, 1984, p. 296–303
D.M.L. Goodgame, J. Chem. Soc., A63 (1966)
C.D. Burbridge and D.M.L. Goodgame, J.Chem.Soc., A, 694 (1967)
N. Ray, S. Tyagi and B. Hathway, J.Chem.Soc. Dalton Trans. 143 (1982).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Majumdar, A., Biswas, M. Polymer anchored metal complexes. Polymer Bulletin 26, 145–150 (1991). https://doi.org/10.1007/BF00297518
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00297518