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Polymer anchored metal complexes

I. Synthesis of 3d-metal complexes of pyromellitic dianhydride-bipyridyl/bipyridylamine polycondensates

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Summary

Pyromellitic dianhydride and dipyridyl/dipyridylamine have been polycondensed in presence of anhydrous ZnCl2 under selective conditions. Fe(III), Cr(III), Co(II), Ni(II) and Cu(II) complexes of the polycondensates have been prepared. Tentative structures for PMDA-DP (DPA)-M complexes have been proposed on the basis of elemental IR and electronic spectral analyses.

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Majumdar, A., Biswas, M. Polymer anchored metal complexes. Polymer Bulletin 26, 145–150 (1991). https://doi.org/10.1007/BF00297518

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