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Synthesis of telechelic monodispersed diols

1. Telomerization of undecylenol with poly(methylene)dithiols

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Summary

The synthesis of telechelic monodispersed diols produced from the radical telomerization of an excess of undecylenol with commercial α, ω poly (methylene) dithiols, HS(CH2)xSH, with x=2,3,5 and 6 initiated by peroxides is presented.

From these dithiols, the diols which were obtained selectively and quantitatively have been characterized by both 1H and 13C-NMR spectroscopy.

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Authors and Affiliations

  1. Ecole Nationale Supérieure de Chimie de Montpellier, URAD11930 CNRS, 8, Rue Ecole Normale, F-34053, Montpellier Cédex 1, France

    Bruno Ameduri, Khalid Berrada & Bernard Boutevin

  2. I.C.I. Materials, Research and Technology Department, The Heath, WA7 4QD, Runcorn, Cheshire, UK

    Roy D. Bowden

Authors
  1. Bruno Ameduri
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  2. Khalid Berrada
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  3. Bernard Boutevin
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  4. Roy D. Bowden
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Ameduri, B., Berrada, K., Boutevin, B. et al. Synthesis of telechelic monodispersed diols. Polymer Bulletin 28, 389–394 (1992). https://doi.org/10.1007/BF00297330

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  • DOI: https://doi.org/10.1007/BF00297330

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