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Ring-opening polymerization of spirobislactones in a solid acrylic matrix

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Summary

Acrylic resins have been made with pendant spirobislactone functional groups. These resins form films at room temperature. When heated at 120°C for 24 h, the films are crosslinked by the reaction of spirobislactone, hydroxyl, and glycidyl groups in the polymer, and an insoluble film is produced.

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Author notes

  1. Allison M. Sikes

    Present address: E. I. duPont de Nemours and Co, P.O. Box 4831, 24115, Martinsville, VA, USA

Authors and Affiliations

  1. Materials Chemistry Branch, Chemistry Division, Naval Research Laboratory, 20375, Washington, DC, USA

    Robert F. Brady Jr. & Allison M. Sikes

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  1. Robert F. Brady Jr.
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  2. Allison M. Sikes
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Brady, R.F., Sikes, A.M. Ring-opening polymerization of spirobislactones in a solid acrylic matrix. Polymer Bulletin 28, 375–380 (1992). https://doi.org/10.1007/BF00297328

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  • DOI: https://doi.org/10.1007/BF00297328

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