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Comb polymer electrolytes

Ionic conductivity and cation-polymer interaction

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Summary

Three comb polymers(CP) with oligo-oxyethylene side chains of the type-O(CH2CH2O)nCH3 were prepared from methyl vinyl ether/maleic anhydride alternating copolymer. Homogeneous amorphous polymer electrolytes were made from CP and LiCF3SO3 or LiClO4 by solvent-casting method, and their conductivities were measured as a function of temperature and salt concentration. The conductivity which displayed non-Arrhenius behaviour was analyzed using the Vogel-Tammann-Fulcher equation. The conductivity maximum appears at lower salt concentration when CP has longer side chains. XPS was used to study the cation-polymer interaction.

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Authors and Affiliations

  1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022, Changchun, People's Republic of China

    Liming Ding

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  1. Liming Ding
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Ding, L. Comb polymer electrolytes. Polymer Bulletin 37, 639–646 (1996). https://doi.org/10.1007/BF00296610

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  • DOI: https://doi.org/10.1007/BF00296610

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