Skip to main content
SpringerLink
Log in

Preliminary analysis of the 1H-NMR and 12C-NMR spectra of poly(2-iodostyrene)

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The 300 MHz 1H-NMR and 75.5 MHz 13C-NMR spectra of poly(2-iodostyrene) were recorded and analyzed in terms of polymer stereochemistry. The aromatic protons were insufficiently resolved for any reasonable peak assignments to be made, but the methine proton resonance could be interpreted in terms of a pentad stereosequence sensitivity. The analysis suggested poly(2-iodostyrene) was an atactic polymer. The 13C-NMR spectrum was somewhat better resolved and analysis supports the results from the 1H-NMR i.e. poly(2-iodostyrene) is an atactic polymer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. L. Trumbo, T. K. Chen and H J. Harwood, Macromolecules, 14, 1138 (1981).

    Google Scholar 

  2. D. L. Trumbo and H. J. Harwood, Polym. Bull., 18, 27 (1987).

    Google Scholar 

  3. D. L. Trumbo and H. J. Harwood, Polym. Bull., 32, 207 (1994).

    Google Scholar 

  4. L. M. Jackman and S. Sternhell, “Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry”, Pergamon Press, NY (1972).

    Google Scholar 

  5. J. L. Koenig, “Chemical Microstructure of Polymer Chains”, J. Wiley and Sons, NY (1980).

    Google Scholar 

  6. H. J. Harwood, T. K. Chen and F. T. Lin, ACS Symposium Series, 247, 197 (1984).

    Google Scholar 

  7. S. J. Tsau, E. R. Santee and H. J. Harwood, ACS Polym. Prep., 31(2), 472 (1990).

    Google Scholar 

  8. T. K. Chen, T. A. Gerkin and H. J. Harwood, Polym. Bull., 2, 34 (1980).

    Google Scholar 

  9. F. W. Wehrli and T. Wirthlin, “Interpretation of Carbon-13 Spectra:, Heyden, NY (1976).

    Google Scholar 

  10. D. L. Trumbo, F. T. Lin, F. M. Lin and H. J. Harwood, Polym. Bull., 28, 87 (1992).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. S. C. Johnson Polymer, S. C. Johnson & Son., Inc., 1525 Howe Street, 53403-2236, Racine, WI, USA

    David L. Trumbo

Authors
  1. David L. Trumbo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Trumbo, D.L. Preliminary analysis of the 1H-NMR and 12C-NMR spectra of poly(2-iodostyrene). Polymer Bulletin 33, 571–577 (1994). https://doi.org/10.1007/BF00296166

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00296166

Keywords

Search

Navigation