Skip to main content
SpringerLink
Log in

EPR investigations of the influence of N,N′-methylene-bisacrylamide (NNMBA) crosslinks on the coordination structure of Cu(II) complexes of poly (N-2-aminoethylacrylamide)s

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The coordination structures of Cu(II) complexes of amino functions supported on polyacrylamides with varying extents of NNMBA-crosslinks were followed by EPR techniques. The geometry of the Cu(II) complexes changes with increasing crosslinking. The covalency of the Cu-N bond also depends on the extent of the NNMBA-crosslinking in the polymer-support.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. Kurimura, Adv. Polym. Sci. 90, 105 (1990).

    Google Scholar 

  2. A. Warshawsky, “Polymeric Ligands in Hydrometallurgy”, in: D.C. Sherrington and P. Hodge (Eds.), “Syntheses and Separations Using Functional Polymers”, J. Wiley, New York, 325 (1988)

    Google Scholar 

  3. M. Kaneko and J. Reedijk, Coord. Chem. Rev. 59, 1 (1981)

    Google Scholar 

  4. A. Tromchimczuk, B.N. Kolarz and M. Wojaezynska, Reactive Polymers, 7, 197 (1988)

    Google Scholar 

  5. D. Lindsay, D. C. Sherrington, J. A. Greig and R. D. Hancock, Reactive Polym. 12, 59 (1990)

    Google Scholar 

  6. H. Nishide and E. Tsuchida, Makromol. Chem. 177, 2295 (1976)

    Google Scholar 

  7. V. K. Sarin, S. B. H. Kent, J. P. Tam and R. B. Merrifield, Anal. Bio. Chem. 46, 774 (1974)

    Google Scholar 

  8. B. K. George and V. N. R. Pillai, Eur. Polym. J. 25, 1099 (1989)

    Google Scholar 

  9. M. Branca, G. Micerea, A. Dessi and H. Koztowski, J. Chem. Soc. Dalton Trans. 1283 (1989)

  10. J. Peisach and W. E. Blumberg, Arch. Biochem. Biophys. 165, 691 (1974)

    Google Scholar 

  11. J. D. Kivelson and R. Neiman, J. Chem. Phys. 35, 149 (1961)

    Google Scholar 

  12. G. Formicka-Kozłowska, H. Kozłowski and B. Jezowska-Trzebiatowska, Inorg. Chim. Acta, 25. 1 (1977).

    Google Scholar 

  13. B. Mathew, P. M. Madhusudanan and V. N. R. Pillai, Thermochim. Acta (In Press)

  14. T. Desai and B. Suther, Syn. Inorg. Chem., 11, 233 (1986)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemical Sciences, Mahatma Gandhi University, Kottayam, 686 631, Kerala, India

    Beena Mathew & V. N. Rajasekharan Pillai

Authors
  1. Beena Mathew
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Rajasekharan Pillai
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mathew, B., Pillai, V.N.R. EPR investigations of the influence of N,N′-methylene-bisacrylamide (NNMBA) crosslinks on the coordination structure of Cu(II) complexes of poly (N-2-aminoethylacrylamide)s. Polymer Bulletin 28, 585–591 (1992). https://doi.org/10.1007/BF00296050

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00296050

Keywords

Search

Navigation