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Anionic polymerization of vinylsilanes

IV. Isomerization polymerization of dimethylphenylvinylsilane

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Summary

The anionic polymerization of dimethylphenylvinylsilane with sec-butyllithium/N,N,N′,N′-tetramethylethylenediamine (TMEDA) was investigated. The polymerization proceeded up to 100% yield and afforded the polymer having isomerized-structure units. The polymerization was accompanied by chain transfer reaction to the monomer and the polymerization rate in the presence of TMEDA was much lower than in the absence of TMEDA.

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Authors and Affiliations

  1. Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466, Nagoya, Japan

    Jun-ichi Oku, Takashi Hasegawa, Yoshiharu Kubota, Mikio Takaki & Ryuzo Asami

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  1. Jun-ichi Oku
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  2. Takashi Hasegawa
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  3. Yoshiharu Kubota
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  4. Mikio Takaki
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  5. Ryuzo Asami
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Oku, Ji., Hasegawa, T., Kubota, Y. et al. Anionic polymerization of vinylsilanes. Polymer Bulletin 28, 505–509 (1992). https://doi.org/10.1007/BF00296039

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  • DOI: https://doi.org/10.1007/BF00296039

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