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Synthesis of telechelic monodispersed diols

2. Telomerization of undecylenol with bis(2-mercapto ethyl) ether and bis(2-mercapto ethyl) sulfide and physical properties

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Summary

The synthesis of telechelic monodispersed diols produced from the radical telomerization of an excess of undecylenol with commercialy available α, ω-dithiols HSC2H4XC2H4SH (X=0, S or CH2) initiated by peroxides is presented. In each case, the diols were obtained selectively and quantitatively and they were characterized by both 1H and 13C NMR. Their physical characteristics (Tg, Tm and decomposition temperatures) were determined. Such compounds are thermally more stable than polydispersed telechelic commercially available diols.

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Authors and Affiliations

  1. URA D11930 CNRS, Ecole Nationale Supérieure de Chimie de Montpellier, 8, Rue Ecole Normale, F-34053, Montpellier Cédex 1, France

    Bruno Ameduri, Khalid Berrada & Bernard Boutevin

  2. I.C.I. Materials, Research and Technology Department, The Heath, WA7 4QD, Runcorn, Cheshire, UK

    Roy D. Bowden

Authors
  1. Bruno Ameduri
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  2. Khalid Berrada
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  3. Bernard Boutevin
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  4. Roy D. Bowden
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Ameduri, B., Berrada, K., Boutevin, B. et al. Synthesis of telechelic monodispersed diols. Polymer Bulletin 28, 497–503 (1992). https://doi.org/10.1007/BF00296038

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  • DOI: https://doi.org/10.1007/BF00296038

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