Summary
The polymerizability of micelle-forming quaternary ammonium monomers, which were derived from a methacrylic ester and styrene, carrying a polymerizable double bond close to the head group (Type H) or at the alkyl chain end (Type T) including a new monomer, 5-(p-vinylphenyl)pentyltrimethylammonium bromide, has been investigated above their critical micelle concentrations in water. The results are explained on the basis of the structure of the obtained polymers as well as the micelle structure of the monomers in water. The Type H monomers were able to thermally polymerize, while the Type T monomers could not.
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References
Paleos CM (1988) J Macromol Sci-Rev Macromol Chem Phys C28: 404;
Pareos CM (1992) “Polymerization in Organized Media”, Paleos CM ed, Gordon and Breach Sci Publ, Philadelphia, pp 183
Aoki S (1995) J Synth Org Chem Jpn 53:423
Dais P, Paleos CM, Nika G, Malliaris A (1993) Makromol Chem 194: 445;
Nika G, Paleos CM, Dais P, Xanakis A, Malliaris A (1992) Progr Colloid Polym Sci 89: 122
Chew CH, Li TD, Gan LM, Teo WK (1995) J Macromol Sci-Pure Appl Chem A32: 211
Yeoh KW, Chew CH, Gan LM, Koh LL, Teo HH (1989) J Macromol Sci-Chem A26: 663
Imae T, Chew CH, Gan LM (1991) Colloids Surf 61: 75
Gan LM, Chew CH (1992) “Organized Solutions—Surfactants in Science and Technology”, Friberg S, Lindman B ed, Mercel Dekker, New York, pp 327
Hamid SM, Scherrington DC (1987) Polymer 28: 325
McGrath KM (1996) Colloid Polym Sci 274: 399
Yasuda Y, Rindo K, Aoki S (1993) Polym J 25: 1203
Cochin D, Candau F, Zana R (1993) Macromolecules 26: 5755
Aoki S, Morimoto Y, Nomura A: to be published
Yasuda Y, Rindo K, Tsushima R, Aoki S (1993) Makromol Chem 194: 1893
Matsumoto A, Tanaka K, Otsu T (1991) Macromolecules 24: 4017
Buback M, et al (1995) Macromol Chem Phys 196: 3267
Matsumoto A, Mizuta K, Otsu T (1993) Macromolecules 26: 1659
Odian G (1991) “Principles of Polymerization”, 3rd ed, Wiley International, New York, pp 286
Laschewsky A, Zerbe I (1991) Polymer 32: 2070
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Aoki, S., Morimoto, Y. Effect of location of polymerizable double bond on the polymerization of micelle-forming monomers. Polymer Bulletin 37, 777–784 (1996). https://doi.org/10.1007/BF00295777
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DOI: https://doi.org/10.1007/BF00295777