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Syndiotactic polymerization of styrene with CpTiCl2(OPri)/methylaluminoxane

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Summary

CpTiCl2(OPri) was a very active catalyst for syndiotactic polymerization of styrene when activated with methyl aluminoxane (MAO). The catalyst activity and syndiospecificity of CpTiCl2(OPri)/MAO were about 107 g PS / mol Ti·mol S·h and about 95% respectively, both higher than those of CpTiCl3 / MAO.

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Authors and Affiliations

  1. Laboratory of Organometallic Chemistry, East China University of Science and Technology, 200237, Shanghai, People's Republic of China

    Jianfei Liu, Jiling Huang, Yanglong Qian & Fan Wang

  2. Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong

    Albert S. C. Chan

Authors
  1. Jianfei Liu
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  2. Jiling Huang
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  3. Yanglong Qian
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  4. Fan Wang
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  5. Albert S. C. Chan
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Liu, J., Huang, J., Qian, Y. et al. Syndiotactic polymerization of styrene with CpTiCl2(OPri)/methylaluminoxane. Polymer Bulletin 37, 719–721 (1996). https://doi.org/10.1007/BF00295768

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  • DOI: https://doi.org/10.1007/BF00295768

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