Summary
The Fourier transform (FT) Raman spectrum of poly (p-phenylene terephthalamide) (Kevlar-49) is reported. Additional bands, not observed in the conventional Raman spectrum, have been assigned. The changes to the FT-Raman spectrum of Kevlar due to the presence of water have also been examined. As a consequence of the intensity changes to certain Raman modes in this preliminary study, it is postulated that water molecules form liquid-like clusters between the crystallite regions of Kevlar fibres.
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References
Chatzi EG, Ishida H and Koenig JL (1986) Appl. Spectrosc. 40: 847
Northolt MG (1974) Eur. Polym. J. 10: 799
Li LS, Allard F and Bigelow WCB (1983) J. Macromol. Sci. Phys. B 22: 269
Penn L and Milanovich F (1979) Polymer 20: 31
Messerschmidt RG and Chase DB (1989) Appl. Spectrosc. 43: 11
Haragushi K, Kajiyama T and Takayanagi M (1979) J. Appl. Polym. Sci. 23: 915
Stuart BH (1994) Polym. Bull. 33: 681
Briscoe BJ, Stuart BH, Thomas PS and Williams DR (1991) Spectrochim. Acta 47A: 1299
Briscoe BJ, Stuart BH, Sebastian S and Tweedale PJ (1993) Wear 162: 407
Stuart BH and Williams DR (1994) Polymer 35: 1326
Konopasek L and Hearle JWS (1977) J. Appl. Polym. Sci. 21: 2791
Rougvie MA and Bear RS (1953) J. Amer. Leather Chem. Assoc. 48: 735
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Stuart, B.H. A Fourier transform Raman study of water sorption by Kevlar-49. Polymer Bulletin 35, 727–733 (1995). https://doi.org/10.1007/BF00294956
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DOI: https://doi.org/10.1007/BF00294956