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Synthesis and chelating properties of poly[(N,N-dicarboxymethyl)allylamine] derived from poly(allylamine)

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Summary

Poly[(N,N-dicarboxymethyl)allylamine] as a water-soluble polymeric chelating agent was prepared by carboxymethylation of poly(allylamine) (PAA) with chloroacetic acid or bromoacetic acid. The 1H-NMR, IR, and elementary analyses showed that the iminodiacetic group was introduced quantitatively into the amino group of PAA. Chelating properties of this polymeric chelating agent toward Cu2+, Ni2+, Zn2+, and Ba2+ were examined by potentiometric titration.

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Authors and Affiliations

  1. Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University, 890, Kagoshima, Japan

    Kensuke Naka, Yoshiyuki Tachiyama, Kiyomi Hagihara, Yasuyuki Tanaka, Mituhiro Yoshimoto, Akira Ohki & Shigeru Maeda

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  1. Kensuke Naka
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  2. Yoshiyuki Tachiyama
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  3. Kiyomi Hagihara
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  4. Yasuyuki Tanaka
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  5. Mituhiro Yoshimoto
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  6. Akira Ohki
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  7. Shigeru Maeda
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Naka, K., Tachiyama, Y., Hagihara, K. et al. Synthesis and chelating properties of poly[(N,N-dicarboxymethyl)allylamine] derived from poly(allylamine). Polymer Bulletin 35, 659–663 (1995). https://doi.org/10.1007/BF00294946

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  • DOI: https://doi.org/10.1007/BF00294946

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