Summary
Mobility of amorphous polymers such as poly(vinyl chloride) (PVC), atactic polypropylene (PPA) and ethylene-propylene-diene terpolymer (EPDM) were studied by proton spin-lattice relaxation time (T1 H), proton spin-lattice relaxation time in the rotating frame (T1Hϱ), and dipolar dephasing pulse sequence. The data are discussed in terms of mobility and by the distribution of configurational sequences.
Similar content being viewed by others
References
Axelson D E, Russell K E (1985) Polym Sci 11: 221
Schaefer J, Stejskal E O in Levy C G ed., “Topics in Carbon-13 NMR Spectroscopy”, 3, John Wiley & Sons, New York, 1979.
Simmons A, Natanshon A (1991) Macromolecules 24: 3651
Feng H, Feng Z, Shen L (1993) Polymer 34: 2516
Stejskal, E O & Memory J D “High Resolution NMR in the Solid State”, Oxford University Press, New York, 1994
Tavares M I B, Monteiro E E C, Harris R K, Kenwright A M (1994) Eur Polym J 30: 1089
Sankar S S, Stejskal E O, Fornes R E, Fleming W W, Russel T P, Wade CG (1992) Polym Fiber Sci, Recent Adv 11: 133
Fyfe CA, “Solid-State NMR for Chemists”, CFC Press, Guelph, 1983
Harris R K, Kenwright A M, Royston A, Say B S (1990) Meas Sci Technol 1: 1304
Silva N M, Tavares M I B (1995) Polymer Testing 14:329
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
da Silva, N.M., Tavares, M.I.B. Mobility study of amorphous polymers by high-resolution NMR at solid-state. Polymer Bulletin 36, 209–212 (1996). https://doi.org/10.1007/BF00294908
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00294908