Skip to main content
Log in

Mobility of additives in ethylene polymers

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Diffusion rate of different additives was studied in ethylene polymers. The measured values were evaluated on the basis of the free-volume theory. It was concluded from the results that the rate of diffusion is primarily determined by the fractional free-volume of the noncrystalline phase of the polymer, as well as the specific volume of the additive.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Moisan JY (1985) Effect of Oxygen Permeation and Stabiliser Migration on Polymer Degradation. In: Comyn J (ed) Polymer Permeability. Elsevier, London New York (chap 4, pp 119–176)

    Google Scholar 

  2. Billingham NC (1990) Physical Phenomena in the Oxidation and Stabilization of Polymers. In: Pospíšil J, Klemchuk PP (eds) Oxidation Inhibition in Organic Materials. CRC Press, Boca Raton FL (vol 2, chap 6, pp 249–297)

    Google Scholar 

  3. Wlochowicz A, Eder M (1984) Polymer 25: 1268

    Google Scholar 

  4. Chiang R, Flory PJ (1961) J Am Chem Soc 93: 2857

    Google Scholar 

  5. Doolittle AK (1951) J Appl Phys 22: 1471

    Google Scholar 

  6. Doolittle AK, Doolittle DB (1957) J Appl Phys 28: 901

    Google Scholar 

  7. Crank J, Park GS (1968) Methods of Measurement. In: Crank J, Park GS (eds) Diffusion in Polymers. Academic Press, London New York (chap 1 pp 1–39)

    Google Scholar 

  8. Crank J (1975) The Mathematics of Diffusion. Clarendon Press, Oxford

    Google Scholar 

  9. Cohen MH, Turnbull D (1959) J Chem Phys 31: 1164

    Google Scholar 

  10. Fujita H (1961) Fortschr Hochpolym-Forsch 3: 1

    Google Scholar 

  11. Földes E (1993) J Appl Polym Sci 48: 1905

    Google Scholar 

  12. Földes E, Turcsányi B (1992) J Appl Polym Sci 46: 507

    Google Scholar 

  13. Földes E (1994) J Appl Polym Sci 51: 1581

    Google Scholar 

  14. Van Krevelen DW, Hoftyzer PJ (1976) Properties of Polymers. Their Estimation and Correlation with Chemical Structure. Elsevier, Amsterdam Oxford New York

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This work was supported by Grant No. OTKA 1/2-1790 from the National Scientific Research Foundation of Hungary.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Földes, E. Mobility of additives in ethylene polymers. Polymer Bulletin 34, 93–99 (1995). https://doi.org/10.1007/BF00294893

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00294893

Keywords

Navigation