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Glass transition temperatures Tg of poly(tolyl methacrylates) and poly(di-xylenyl itaconates)

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Summary

Glass transition temperatures of poly(phenyl methacrylates) and poly(diphenyl itaconats) with one and two methyl substituents in the phenyl ring were determined by DSC. Within the group of 17 investigated polymers it was attempted to correlate the Tg values obtained with the polymer repeat unit structure, considering steric effects and dipole/dipole interactions, inherent to various modes of (di)substitution.

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Authors and Affiliations

  1. Faculty of Technology and Metallurgy, University of Beograd, Karnegijeva 4, YU-11000, Beograd, Yygoslavia

    J. S. Veličković, J. M. Filipović, M. B. Plavsić & D. M. Petrović-Djakov

  2. Faculty of Technology, University of Novi Sad, YU-21000, Novi Sad, Yugoslavia

    Z. S. Petrović & J. K. Budinski

Authors
  1. J. S. Veličković
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  2. J. M. Filipović
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  3. M. B. Plavsić
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  4. D. M. Petrović-Djakov
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  5. Z. S. Petrović
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  6. J. K. Budinski
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Dedicated to Prof. Dragutin Fleš on the occasion of his 70th birthday

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Veličković, J.S., Filipović, J.M., Plavsić, M.B. et al. Glass transition temperatures Tg of poly(tolyl methacrylates) and poly(di-xylenyl itaconates). Polymer Bulletin 27, 331–336 (1991). https://doi.org/10.1007/BF00294540

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  • DOI: https://doi.org/10.1007/BF00294540

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