Summary
The nature of the excited state interactions in poly(ethylene terephthalate) is still subject to debate. We study a new series of model compounds composed of a central terephthaloyl group condensed with α-hydroxy-ω-phenyl-n-alkanes. Although the molecular architecture prevents these molecules from achieving symmetric ring-ring overlap, the steady-state fluorescence spectra are remarkably similar to those of other models studied earlier, where such overlap was expected. The solvent polarity dependence suggests that the excited state complex is an exciplex and not an excimer.
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References
Birks JW (1970) Photophysics of Aromatic Molecules Wiley-Interscience, London
Mataga N, Kubota T (1970) Molecular Interactions and Electronic Spectra Marcel Dekker, New York
Winnik M (1986) in Photophysical and Photochemical Tools in Polymer Science Winnik M (ed), NATO ASI Series C Vol. 182, Reidel, Dordrecht, p 293
Hirayama F (1965) J. Chem. Phys. 42:3163
Phillips D, Shug J (1969) J. Chem. Phys. 50:3297
Takai Y, Osawa T, Mizutani T, Ieda M (1977) J. Polym. Sci., Polym. Phys. Ed. 15:945
Allen N, McKellar J (1978) Makromol. Chem. 179:523
Hemker D, Frank C, Thomas J (1988) Polymer 29:437
Chen L, Jin X, Du J, Qian R (1991) Makromol. Chem. 192:1399
LaFemina J, Arjavalingam G (1991) J. Phys. Chem. 95:984
Dodge R, Mattice WL (1993) J. Polym. Sci.: Part B: Polym. Phys. 31:207
Mendicuti F, Patel B, Waldeck DH, Mattice WL (1989) Polymer 30:1680
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Matties, M.A., Mattice, W.L. Photophysical models of aromatic polyesters: excited state interactions in bis(phenalkyl)terephthalate. Polymer Bulletin 34, 369–375 (1995). https://doi.org/10.1007/BF00294157
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DOI: https://doi.org/10.1007/BF00294157