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Polymer Bulletin

, Volume 34, Issue 3, pp 331–335 | Cite as

Solubilization control by redox-switching of polysoaps

  • P. Anton
  • A. Laschewsky
  • M. D. Ward
Article

Summary

Reversible changes in the self-organization of polysoaps may be induced by controlling their charge numbers via covalently bound redox moieties. This is illustrated with two viologen polysoaps, which in response to an electrochemical stimulus, change their solubility and aggregation in water, leading from homogeneously dissolved and aggregated molecules to collapsed ones and vice verse. Using the electrochemical quartz crystal microbalance (EQCM), it could be shown that the reversibility of this process is better than 95% in 16 cycles.

Keywords

Polymer Quartz Material Processing Verse Quartz Crystal 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1995

Authors and Affiliations

  • P. Anton
    • 2
  • A. Laschewsky
    • 1
  • M. D. Ward
    • 3
  1. 1.Université Catholique de LouvainDépt. de ChimieLouvain-la-NeuveBelgium
  2. 2.Institut für ChemieUniversität MainzMainzGermany
  3. 3.Department of Chemical Engineering and Materials ScienceUniversity of MinnesotaMinneapolisUSA

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