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Determination of the monomer donor-acceptor complexes participation in the alternating propagating reaction based on the microtacticity of the alternating copolymers

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Summary

It is shown that the probability for the formation of alternating macromolecules by monomer donor-acceptor complexes can be determined from the microtacticity of the copolymers. If the stereoregularity in the alternating copolymerization is described by the Bernoullian trial two other probabilities concerning the meso-diad formation can be determined by this method. If the stereoregularity is described by the first order Markov chain the transition probabilities can be calculated. Thus a more detailed analysis of the propagation mechanism in alternating copolymerization can be carried out.

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References

  • G. S. GEORGIEV: Annuaire de l'Université de Sofia, Faculté de Chimie 70, 169 (1975)

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Authors and Affiliations

  1. Department of Chemistry, University of Sofia, 1126, Sofia, Bulgaria

    George S. Georgiev & Vitaly P. Zubov

  2. Department of Chemistry, Moscow Lomonosov University, B-234, Moscow, USSR

    Vitaly P. Zubov

Authors
  1. George S. Georgiev
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  2. Vitaly P. Zubov
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Additional information

Thanks are due to Professor V. A. KABANOV and Dr. V. B. GOLUBEV from Moscow Lomonosov University for stimulating discussions.

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Georgiev, G.S., Zubov, V.P. Determination of the monomer donor-acceptor complexes participation in the alternating propagating reaction based on the microtacticity of the alternating copolymers. Polymer Bulletin 1, 441–444 (1979). https://doi.org/10.1007/BF00284417

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  • DOI: https://doi.org/10.1007/BF00284417

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